树枝状多孔二氧化硅纳米粒子的制备及其在先进载体中的应用

杜鑫; 赵彩霞; 黄洪伟; 温永强; 张学记

doi:10.7536/PC160209

化学进展 ›› 2016, Vol. 28 ›› Issue (8) :1131-1147 DOI: 10.7536/PC160209

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树枝状多孔二氧化硅纳米粒子的制备及其在先进载体中的应用

^1*

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Synthesis of Dendrimer-Like Porous Silica Nanoparticles and Their Applications in Advanced Carrier

Du Xin^1*, Zhao Caixia¹, Huang Hongwei², Wen Yongqiang¹, Zhang Xueji¹

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摘要

树枝状多孔二氧化硅纳米粒子具有中心辐射状孔道结构且孔道尺寸从粒子内部到粒子表面逐渐增加，是一种具有新颖结构的多孔材料。和传统的具有二维六方有序孔道结构的介孔二氧化硅粒子相比，这种粒子具有三维开放性的树枝状骨架结构，因而具有独特的结构优势，即高的孔渗透性和高的粒子内表面的可接触性，从而有利于物质（分子或纳米粒子）沿着中心辐射状的孔道进行输送，在树枝状粒子的内部负载或者与内部的活性位点发生反应。因此，这种粒子是一种很有前景的载体平台，可以用来构筑新型的吸附剂、纳米催化剂和基因药物的递送系统等。本综述首先介绍了一系列的合成方法和对树枝状骨架结构的调控策略，探讨了树枝状多孔结构对物理化学性能的影响，描述了其在催化、纳米生物医学、环境能源等领域的应用性能，并对树枝状多孔二氧化硅粒子的合成方向和应用前景进行了展望。

Abstract

Dendrimer-like porous silica nanoparticles, which have center-radial pore structures with gradually increasing pore sizes from particle interior to particle surface, are a kind of new porous material. Compared with conventional mesoporous silica nanoparticles (MSNs) with uniform hexagonal ordered mesopores, dendrimer-like nanoparticles have remarkable structure advantages due to their unique open three-dimensional dendritic superstructures, such as high pore permeability and high accessibility to internal surface, thus being in favor of mass (molecules and even nanoparticles) transfer process along center-radial pore channels, loading in the interior of dendritic nanoparticles or reacting with active sites in the particles. Therefore, they are very promising platforms to construct advanced adsorbents, nanocatalysts and drugs and gene nanocarriers. In this review, we first introduce a series of synthesis methods and the intrinsic mechanism about how to regulate the dendritic structure, then analyze their unique structural characteristics and the corresponding physicochemical properties, subsequently present a few examples of interesting applications mainly in catalysis, biomedicine, environment and energy, and other important fields, finally conclude with an outlook on the prospects and challenges in terms of their controlled synthesis and potential applications.

Contents
1 Introduction
2 Structural characteristics and properties
3 Synthesis strategies
3.1 Oil-water biphase stratification method
3.2 Special microemulsion systems
3.3 Dynamic ethyl ether emulsion systems
3.4 Dynamic polystyrene template
3.5 Soft template caused by strong counterion
3.6 Other approaches
4 Applications
4.1 Catalysis
4.2 Biomedical and biotechnological applications
4.3 Other applications

Graphical abstract

关键词

树枝状多孔结构 / 中心辐射状孔道 / 二氧化硅 / 纳米粒子 / 载体

Key words

dendrimer-like porous structure / center-radial channels / silica / nanoparticles / carrier

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杜鑫, 赵彩霞, 黄洪伟, 温永强, 张学记. 树枝状多孔二氧化硅纳米粒子的制备及其在先进载体中的应用[J]. 化学进展, 2016, 28(8): 1131-1147 DOI:10.7536/PC160209

Du Xin, Zhao Caixia, Huang Hongwei, Wen Yongqiang, Zhang Xueji. Synthesis of Dendrimer-Like Porous Silica Nanoparticles and Their Applications in Advanced Carrier[J]. Progress in Chemistry, 2016, 28(8): 1131-1147 DOI:10.7536/PC160209

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