溶液法制备有机太阳电池阳极界面修饰层MoO3

李炎平; 於黄忠; 董一帆; 黄欣欣

doi:10.7536/PC160336

化学进展 ›› 2016, Vol. 28 ›› Issue (8) :1170-1185 DOI: 10.7536/PC160336

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溶液法制备有机太阳电池阳极界面修饰层MoO₃

^1,2

^1*

作者信息 +

Anode Interface Modification of Organic Solar Cells with Solution-Prepared MoO₃

Li Yanping^1,2, Yu Huangzhong^1*, Dong Yifan², Huang Xinxin²

Author information +

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摘要

在全溶液低温制备高效、稳定有机光伏器件过程中，合理选择制备器件界面修饰材料的方法至关重要，它已成为近期有机光伏领域的重点研究内容之一。合理的界面材料能降低界面的势垒高度，减少器件的串联电阻。溶液法制备三氧化钼（MoO₃）阳极界面缓冲层能有效地改善有机太阳电池阳极界面收集和载流子传输的效率，从而提高太阳电池能量转换效率，同时也提高太阳电池的稳定性。本文综述了近年来溶液法制备有机太阳电池阳极界面修饰层MoO₃的研究进展，介绍了阳极界面修饰层MoO₃的各种制备方法与原理，阐述了基于溶液法制备界面修饰层MoO₃薄膜的研究现状与存在问题，以期为全溶液法制备高效稳定有机太阳电池的研究提供有价值的参考。

Abstract

For the whole solution-processed efficient and stable organic photovoltaic devices at low temperature, reasonably selecting the method of interface modification material preparation is very crucial. It has become one of the most focuses in research community of organic photovoltaics in recent years. By choosing suitable interfacial materials, the energetic barrier height at the interface could be reduced to form an ohmic contact with less series resistance, inducing high charge collection efficiency of the corresponding electrodes for holes or electrons. Solution-prepared molybdenum oxide (MoO₃) as anode buffer layer can effectively improve the efficiency of interface collection and carrier transmission, improving the energy conversion efficiency and stability of organic solar cells. This article reviews the research progress of anode buffer layer MoO₃ of organic solar cells in recent years, introduces the some preparation methods and principles of MoO₃ as anode interface layers, elaborated the current situation and existing problems of MoO₃ film based on the prepared solution of interfacial modification, which provides valuable references for the fabrication of the efficient and stable organic solar cells. We believe that solution-processed MoO₃ will play a key role as buffer layers in the future fabrication of large area and flexible organic photovoltaic devices with high performance and long term stability.

Contents
1 Introduction
2 The effect of solution-prepared of MoO₃ anode interface modification
3 The energy level structure and change of MoO₃
4 The application of solution-prepared MoO₃ in organic solar cell
4.1 MoO₃based on the preparation of ammonium molybdate
4.2 MoO₃ based on organic molybdenum sources
4.3 MoO₃ prepared by chemical synthesis
4.4 MoO₃ prepared by nanoparticle dispersion method
4.5 MoO₃ prepared by other solutions
5 Conclusion

Graphical abstract

关键词

溶液法 / 三氧化钼薄膜 / 有机太阳电池 / 阳极界面修饰

Key words

solution method / molybdenum oxide film / organic solar cells / anode interface modification

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李炎平, 於黄忠, 董一帆, 黄欣欣. 溶液法制备有机太阳电池阳极界面修饰层MoO₃[J]. 化学进展, 2016, 28(8): 1170-1185 DOI:10.7536/PC160336

Li Yanping, Yu Huangzhong, Dong Yifan, Huang Xinxin. Anode Interface Modification of Organic Solar Cells with Solution-Prepared MoO₃[J]. Progress in Chemistry, 2016, 28(8): 1170-1185 DOI:10.7536/PC160336

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