选择性氧化还原脱硝催化剂

李盼盼; 于锋; 朱明远; 汤常金; 代斌; 董林

doi:10.7536/PC160350

化学进展 ›› 2016, Vol. 28 ›› Issue (10) :1578-1590 DOI: 10.7536/PC160350

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选择性氧化还原脱硝催化剂

^1,3,4

^2,5

^1*

^2,5*

作者信息 +

Selective Catalytic Reduction De-NO_x Catalysts

Li Panpan¹, Yu Feng^1,3,4, Zhu Mingyuan¹, Tang Changjin^2,5, Dai Bin^1*, Dong Lin^2,5*

Author information +

文章历史 +

摘要

氮氧化物（NO_x）是烟气中的主要污染性气体之一，脱除NO_x已经刻不容缓。本文综述了近年来烟气中NO_x的脱除方法，分析了以钒基催化剂、铁基催化剂、分子筛催化剂为代表的高温脱硝催化剂，讨论了以贵金属催化剂、锰基催化剂、碳基催化剂为代表的低温脱硝催化剂，阐述了不同温度下选择性催化还原（SCR）脱硝催化剂的反应机理，展望了脱硝领域的发展前景。

Abstract

Nitrogen oxides (NO_x) in flue gases is an important source of air pollution. It is urgent to remove the NO_x from flue gases. In this review, the removal ways of nitrogen oxides are reviewed in terms of high-temperature and low-temperature selective catalytic reduction (SCR) De-NO_x catalysts. We discuss the high-temperature SCR De-NO_x catalysts including vanadium-based catalysts, iron-based catalysts and molecular sieve-based catalysts. Then, we highlight the low-temperature SCR De-NO_x catalysts such as noble metal-based catalysts, manganese-based catalyst, carbon-based catalysts, etc. We specifically focus on the mechanism studies of SCR De-NO_x catalysts. Finally, we summarize the recent advances in denitrification.

Contents
1 Introduction
2 Process arrangement of SCR denitrification
3 SCR catalysts
3.1 High-temperature catalysts
3.2 Low-temperature catalysts
4 Conclusion

Graphical abstract

关键词

氮氧化物 / 选择性催化还原 / 脱硝催化剂 / 反应机理

Key words

nitrogen oxides / selective catalytic reduction / denitrification catalyst / reaction mechanism

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李盼盼, 于锋, 朱明远, 汤常金, 代斌, 董林. 选择性氧化还原脱硝催化剂[J]. 化学进展, 2016, 28(10): 1578-1590 DOI:10.7536/PC160350

Li Panpan, Yu Feng, Zhu Mingyuan, Tang Changjin, Dai Bin, Dong Lin. Selective Catalytic Reduction De-NO_x Catalysts[J]. Progress in Chemistry, 2016, 28(10): 1578-1590 DOI:10.7536/PC160350

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