沸石咪唑酯骨架材料用于水中污染物的去除

范功端; 林茹晶; 苏昭越; 许仁星

doi:10.7536/PC160433

化学进展 ›› 2016, Vol. 28 ›› Issue (12) :1753-1761 DOI: 10.7536/PC160433

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沸石咪唑酯骨架材料用于水中污染物的去除

^1,2*

作者信息 +

Removing Water Contaminants Using Zeolitic Imidazolate Frameworks

Fan Gongduan^1,2*, Lin Rujing¹, Su Zhaoyue¹, Xu Renxing¹

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摘要

当前水污染问题严重制约了国民经济和社会的发展，对水污染的控制与治理具有重大研究意义且刻不容缓。沸石咪唑酯骨架结构材料（zeolitic imidazolate frameworks，ZIFs）作为新兴化学与材料科学相结合产物，凭借其结构稳定、比表面积大和性能优良等特点在全球范围内受到广泛关注，并逐步应用于去除水中的污染物。本文以ZIF-8为代表，综述沸石咪唑酯骨架材料去除水中污染物的研究与进展，系统介绍了其作为吸附剂及光催化剂对水中污染物的去除效果，总结了ZIFs制备条件和环境因素对其去除水中污染物的影响，并对今后的研究进行了展望，以期为ZIFs材料应用于实际污染水体的处理提供理论支撑。

Abstract

The vigorous increase of the frequency of water pollution has become serious bottlenecks constraining national economy and modern industry development. Therefore, the research on the control and treatment of water contaminants is of great significance and urgency. Zeolitic imidazolate frameworks (ZIFs), as a product of chemical and material science that have been rapidly developing in recent years, have received extensive attention around the world and have been applied to waste water treatment owing to their stable structure, high surface area and excellent performance. Taking the ZIF-8 as the representative, this paper reviews the research and development on the application of ZIFs to remove water contaminants. The performance of the ZIFs in removal of water contaminants as the adsorbent and photocatalyst is introduced systematically, the factors influencing water contaminants removal by ZIFs are summed up. Moreover, it has carried on the forecast to later period's research. The objective of this paper is to provide theoretical reference for the practical application of ZIFs to the treatment of real waste water.

Contents
1 Introduction
2 Effect of ZIFs on the removal of water contaminants
2.1 Removal efficiency of ZIFs as adsorbent for water contaminants
2.2 Removal efficiency of water contaminants by ZIFs used as photocatalyst
3 Factors influencing removal of water contaminants by ZIFs
3.1 Preparation of ZIFs for the removal of water contaminants
3.2 Environmental impact of ZIFs on the removal of water contaminants
4 The mechanism of water contaminants removal by ZIFs
4.1 ZIFs as adsorbent
4.2 ZIFs as photocatalyst
5 Conclusions

Graphical abstract

关键词

沸石咪唑酯骨架结构材料 / 水中污染物 / 吸附 / 光催化 / 废水处理

Key words

zeolitic imidazolate frameworks / water contaminants / adsorption / photocatalysis / waste water treatment

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范功端, 林茹晶, 苏昭越, 许仁星. 沸石咪唑酯骨架材料用于水中污染物的去除[J]. 化学进展, 2016, 28(12): 1753-1761 DOI:10.7536/PC160433

Fan Gongduan, Lin Rujing, Su Zhaoyue, Xu Renxing. Removing Water Contaminants Using Zeolitic Imidazolate Frameworks[J]. Progress in Chemistry, 2016, 28(12): 1753-1761 DOI:10.7536/PC160433

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