非TiO2光催化剂去除气态VOCs

张晓东; 杨阳; 李红欣; 邹学军; 王玉新

doi:10.7536/PC160516

化学进展 ›› 2016, Vol. 28 ›› Issue (10) :1550-1559 DOI: 10.7536/PC160516

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非TiO₂光催化剂去除气态VOCs

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作者信息 +

Non-TiO₂ Photocatalysts Used for Degradation of Gaseous VOCs

Zhang Xiaodong^1*, Yang Yang¹, Li Hongxin¹, Zou Xuejun^2*, Wang Yuxin^3*

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文章历史 +

摘要

本文综述了近年来非TiO₂光催化剂降解气态挥发性有机物（VOCs）的研究现状。对一些有代表性的新型光催化剂，如金属氧化物、宽带隙p区金属氧化物/氢氧化物、钙钛矿类、尖晶石类、铋系化合物、钒系化合物等的结构与光催化性能之间的关系进行分析。另外，本文从VOCs初始浓度、流速、光源、光强、温度、湿度等光催化反应的工艺条件出发，概述了工艺参数对VOCs废气净化效果影响的研究进展；并对目前非TiO₂光催化剂研究中存在的主要问题进行总结并展望。

Abstract

In this paper, research progress about the utilization of non-TiO₂ photocatalysts in degradation of gaseous VOCs are reviewed. We give a concise overview of several novel non-TiO₂ photocatalysts with a focus in their structure, which affect the catalytic activities, including metal oxide, wide bandgap p-block metal oxides/hydroxides, perovskite-type, spinel-type, bismuth based compounds, vanadium based compounds, et al. In addition, the research progress of influence factors of non-TiO₂ photocatalytic purification of gaseous VOCs exhaust is summarized from photocatalytic reaction conditions (such as VOCs initial concentration, flow rate, light source, light intensity, reaction temperature and humidity). Finally, the fundamental challenges and perspectives of non-TiO₂ photocatalysts are briefly brought up.

Contents
1 Introduction
2 Non-TiO₂ photocatalytic oxidation of VOCs
2.1 Metal oxide photocatalysts
2.2 Wide bandgap p-block metal oxides/hydroxides photocatalysts
2.3 Perovskite-type oxides photocatalysts
2.4 Spinel-type photocatalysts
2.5 Bismuth based photocatalysts
2.6 Vanadium based photocatalysts
2.7 Other photocatalysts
3 The effect of process parameters on VOCs purification
3.1 The initial concentration of VOCs and flow rate
3.2 The light source and light intensity
3.3 Temperature and humidity
3.4 Other parameters
4 Conclusion and outlook

Graphical abstract

关键词

非TiO₂光催化剂 / 挥发性有机物 / 环境净化 / 机理

Key words

non-TiO₂ photocatalysts / volatile organic compounds / environmental purification / mechanism

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张晓东, 杨阳, 李红欣, 邹学军, 王玉新. 非TiO₂光催化剂去除气态VOCs[J]. 化学进展, 2016, 28(10): 1550-1559 DOI:10.7536/PC160516

Zhang Xiaodong, Yang Yang, Li Hongxin, Zou Xuejun, Wang Yuxin. Non-TiO₂ Photocatalysts Used for Degradation of Gaseous VOCs[J]. Progress in Chemistry, 2016, 28(10): 1550-1559 DOI:10.7536/PC160516

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