二维Z型光催化材料及其在环境净化和太阳能转化中的应用

张圆正; 谢利利; 周怡静; 殷立峰*

doi:10.7536/PC160617

化学进展 ›› 2016, Vol. 28 ›› Issue (10) :1528-1540 DOI: 10.7536/PC160617

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二维Z型光催化材料及其在环境净化和太阳能转化中的应用

张圆正, 谢利利, 周怡静, 殷立峰*

作者信息 +

2D Z-Scheme Photocatalyst and Its Application in Environmental Purification and Solar Energy Conversion

Zhang Yuanzheng, Xie Lili, Zhou Yijing, Yin Lifeng*

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文章历史 +

摘要

光催化技术可将太阳能转化为可存储能源，还可直接利用太阳能分解污染物，是缓解能源紧张，净化环境的有效途径。Z型光催化体系可模拟光合作用过程，在可见光下具有较高的光能转化效率，成为近年来的研究热点，而碳化氮等二维纳米材料的发展进一步启发人们基于微观二维结构构建Z型光催化体系，以强化其光谱响应能力、载流子分离效率、氧化还原能力以及光蚀稳定性。本文综述了近年来二维Z型光催化材料在基础理论，合成方法方面的研究进展及其在环境和能源领域的应用情况，并对二维Z体系在光催化领域的研究前景进行了展望。

Abstract

Photocatalysis, which not only converts solar energy into storable energy but also directly employs solar energy to decompose environmental pollutants, is one of the effective ways to alleviate the shortage of energy and remediate environment. The Z-scheme photocatalysts can simulate the natural photosynthesis process with high photocatalytic activity under visible light irradiation, becoming a research hotspot in recent years. The development of emerging carbonization nitrogen and graphene-like two-dimensional nanomaterials inspire people to build Z-scheme photocatalytic systems based on two dimensional nanostructure. By this means, the optical spectrum response, carriers separation capacity, redox potentials, and stability to resist light-etch of Z-scheme photocatalysts are reinforced. This paper reviews the recent progress in the study of two dimensional Z-scheme photocatalytic materials, introduces the preparation methods, reaction mechanisms and applications of two dimensional Z-scheme photocatalysts in the field of environment purification and solar energy conversion. Finally, the research prospects of two-dimensional Z-scheme materials in the field of photocatalysis are briefly proposed.

Contents
1 Introduction
2 Study on mechanism of two dimensional Z-scheme photocatalysis
2.1 Reaction mechanism of Z-scheme photocatalysis
2.2 Characteristics and functions of two dimensional Z-scheme photocatalyst
3 Novel two-dimensional visible light catalysts and its control synthesis
3.1 Graphite-phase carbon nitride (g-C₃N₄)
3.2 Sulfide
3.3 Bismuth based photocatalyst
4 Application of two dimensional Z-scheme visible light responsive photocatalyst in the field of pollutant control
4.1 Photocatalytic degradation of dyes
4.2 Photocatalytic degradation of phenols
4.3 Photocatalytic degradation of antibiotics
5 Application of two dimensional Z-scheme visible light responsive photocatalyst in the energy conversion
5.1 Photocatalytic hydrogen production
5.2 Photocatalytic reduction of CO₂
6 Conclusion

Graphical abstract

关键词

二维Z体系 / 可见光 / 降解 / 制氢 / 还原二氧化碳

Key words

two dimensional Z-scheme / visible light / degradation / hydrogen production / reduction of carbon dioxide

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张圆正, 谢利利, 周怡静, 殷立峰*. 二维Z型光催化材料及其在环境净化和太阳能转化中的应用[J]. 化学进展, 2016, 28(10): 1528-1540 DOI:10.7536/PC160617

Zhang Yuanzheng, Xie Lili, Zhou Yijing, Yin Lifeng*. 2D Z-Scheme Photocatalyst and Its Application in Environmental Purification and Solar Energy Conversion[J]. Progress in Chemistry, 2016, 28(10): 1528-1540 DOI:10.7536/PC160617

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