Li-Mg-N-H体系储氢材料的热力学和动力学调控

李超; 范美强; 陈海潮; 陈达; 田光磊; 舒康颖

doi:10.7536/PC160619

化学进展 ›› 2016, Vol. 28 ›› Issue (12) :1788-1797 DOI: 10.7536/PC160619

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Li-Mg-N-H体系储氢材料的热力学和动力学调控

^1,2*

^1*

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Thermodynamics and Kinetics Modifications on the Li-Mg-N-H Hydrogen Storage System

Li Chao^1,2*, Fan Meiqiang¹, Chen Haichao¹, Chen Da¹, Tian Guanglei¹, Shu Kangying^1*

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摘要

Mg（NH₂）₂-2LiH体系储氢材料具有较高的储氢容量和较适宜的热力学性能，并且其吸放氢过程完全可逆，是目前最有望实现大规模应用的固态储氢材料之一。然而，由于该体系在吸放氢过程中具有较高的动力学壁垒，导致其在200℃以上才能实现快速地吸放氢。因此，国际上对该体系储氢材料的研究主要集中在热力学和动力学的调控方面。本文从成分调变、纳米化和掺杂改性等方面，详细综述了Mg（NH₂）₂-2LiH体系储氢材料热力学和动力学调控的研究现状，并提出了其中存在的问题和相应对策，同时指出了将来的研究方向。

Abstract

Mg(NH₂)₂-2LiH system possesses a higher reversible hydrogen storage capacity and favorable thermodynamics, consequently being regarded as one of the most promising hydrogen storage materials. However, a temperature above 200℃ is needed to obtain quick de-/hydrogenation because of a rather high kinetic barrier. As a result, numerous investigations have been attempted to adjust the hydrogen storage thermodynamics and kinetics properties. Starting from the three aspects of material composites, nanocrystallization and modification by doping, the progress in the hydrogen storage thermodynamics and kinetics is systematically summarized in this review. The challenges and countermeasures are illustrated, and the direction to further enhancing the hydrogen storage properties of the Mg(NH₂)₂-2LiH system is also pointed out.

Contents
1 Introduction
2 Compositional manipulation of the Li-Mg-N-H system
3 Nanosized Li-Mg-N-H system
4 Modification by doping
4.1 The effect of transition metals and their compounds
4.2 The effect of carbon-based materials
4.3 The effect of metal borohydrides
4.4 The effect of alkali metal-based compounds
4.5 The effect of other dopants
5 Conclusion

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关键词

储氢材料 / 热力学 / 动力学 / 氨基物 / 氢化物 / 性能调控

Key words

hydrogen storage materials / thermodynamics / kinetics / amides / hydrides / performance adjustment

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李超, 范美强, 陈海潮, 陈达, 田光磊, 舒康颖. Li-Mg-N-H体系储氢材料的热力学和动力学调控[J]. 化学进展, 2016, 28(12): 1788-1797 DOI:10.7536/PC160619

Li Chao, Fan Meiqiang, Chen Haichao, Chen Da, Tian Guanglei, Shu Kangying. Thermodynamics and Kinetics Modifications on the Li-Mg-N-H Hydrogen Storage System[J]. Progress in Chemistry, 2016, 28(12): 1788-1797 DOI:10.7536/PC160619

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