菱沸石在柴油车尾气NOx催化净化中的应用

谢利娟; 石晓燕; 刘福东; 阮文权

doi:10.7536/PC160731

化学进展 ›› 2016, Vol. 28 ›› Issue (12) :1860-1869 DOI: 10.7536/PC160731

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菱沸石在柴油车尾气NO_x催化净化中的应用

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^1,2*

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Selective Catalytic Reduction of NO_x from Diesel Engine with NH₃ over Zeolites Catalysts with Chabazite

Xie Lijuan^1,2, Shi Xiaoyan^3,4, Liu Fudong^3,4, Ruan Wenquan^1,2*

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摘要

柴油车尾气NO_x控制是目前大气污染控制领域的重要研究内容，对改善城市大气污染现状有着极其重要的作用。NH₃选择性催化还原NO_x（NH₃-SCR）是应用于该领域的主流技术之一。近年来，以具有菱沸石（chabazite，CHA）结构的分子筛为载体负载Cu制备的Cu-CHA（Cu-SSZ-13和Cu-SAPO-34）系列催化剂，因其优秀的NH₃-SCR活性和良好的水热稳定性，成为学者们关注的热点。本文首先从制备方法及反应条件对Cu-CHA催化性能的影响和NH₃-SCR反应机理这几个方面系统阐述Cu基菱沸石在柴油车尾气NO_x催化净化领域的研究进展；然后总结了负载其他过渡金属和稀土金属制备的M-CHA分子筛催化剂在NH₃-SCR反应中的应用，指出双活性中心菱沸石催化剂在NH₃-SCR领域表现出的优势；在此基础上对菱沸石NH₃-SCR催化剂的进一步改良做出展望。

Abstract

The purification of NO_x from diesel engine exhaust is an important topic in the field of air pollution control, which is significant for the improvement of current unban air quality. The selective catalytic reduction of NO_x with NH₃ (NH₃-SCR) is one of the most promising technologies for the control of NO_x emission from diesel engine exhaust. In recent years, Cu-CHA catalysts, which are obtained from loading transition metal Cu on zeolites with chabazite (CHA) structure, have attracted much attention in the field of NH₃-SCR reaction, due to their excellent NH₃-SCR activity and hydrothermal stability. Cu-SSZ-13 and Cu-SAPO-34 are the two typical Cu-CHA catalysts. In this review, the progress of NO_x control in the field of diesel engine exhaust with Cu-CHA catalysts is stated from three aspects firstly, including the influences of preparation method, the effects of reaction condition and the NH₃-SCR reaction mechanism. Then, the application of M-CHA catalysts in NH₃-SCR reaction are elaborated, where M is limited as some other transition metal and rare earth metal. Meanwhile, the advantages of bimetallic-based CHA zeolites in NH₃-SCR reaction are identified. Based on these results, the possible improvement orientations for NH₃-SCR catalysts with CHA zeolites structure are also prospected.

Contents
1 Introduction
2 Application of Cu-CHA catalysts in NH₃-SCR
2.1 Cu-SSZ-13 used for NO_x purification
2.2 Cu-SAPO-34 used for NO_x purification
3 Application of Fe-CHA catalysts in NH₃-SCR
4 Application of bimetallic active center catalysts with CHA structure in NH₃-SCR
5 Conclusion and outlook

Graphical abstract

关键词

NO_x控制 / NH₃选择性催化还原 / 菱沸石 / 反应机理 / 双活性中心

Key words

NO_x control / selective catalytic reduction of NH₃ / chabazite / reaction mechanism / bimetallic active center

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谢利娟, 石晓燕, 刘福东, 阮文权. 菱沸石在柴油车尾气NO_x催化净化中的应用[J]. 化学进展, 2016, 28(12): 1860-1869 DOI:10.7536/PC160731

Xie Lijuan, Shi Xiaoyan, Liu Fudong, Ruan Wenquan. Selective Catalytic Reduction of NO_x from Diesel Engine with NH₃ over Zeolites Catalysts with Chabazite[J]. Progress in Chemistry, 2016, 28(12): 1860-1869 DOI:10.7536/PC160731

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