体异质结型聚合物太阳能电池中的微观形貌调控方法

康建喜; 王世荣; 孙孟娜; 刘红丽; 李祥高

doi:10.7536/PC161213

化学进展 ›› 2017, Vol. 29 ›› Issue (4) :400-411 DOI: 10.7536/PC161213

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体异质结型聚合物太阳能电池中的微观形貌调控方法

^1,2,3

^1,2,3*

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Regulation Methods for Micro-Morphology of Bulk Heterojunction Polymer Solar Cells

Jianxi Kang^1,2,3, Shirong Wang^1,2,3, Mengna Sun^1,2,3, Hongli Liu^1,2,3, Xianggao Li^1,2,3*

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摘要

体异质结型聚合物太阳能电池因具有成本低、质量轻、制备工艺简单和柔韧性好等优点，成为光伏技术领域的研究热点，其能量转化效率超过11%。体异质结层作为体异质结型聚合物太阳能电池的核心，其微观形貌影响体异质结型聚合物太阳能电池的开路电压、填充因子和短路电流，进而影响其能量转化效率。因此如何有效调控体异质结的微观形貌是提高体异质结型聚合物太阳能电池能量转换效率的关键问题之一。本文系统介绍了体异质结的形成过程，总结和论述近年发展的体异质结的微观形貌调控方法，以期为体异质结型聚合物太阳能电池的制备提供指导和借鉴。

Abstract

Bulk heterojunction polymer solar cells have become one of the research hotspots in the field of photovoltaic technology due to their low production cost, light weight, simple preparation process, good flexibility and so on. Bulk heterojunction polymer solar cells have achieved energy conversion efficiency of more than 11%. The bulk heterojunction layer is the key point of the bulk heterojunction polymer solar cells and its micro-morphology has an influence on the energy conversion efficiency by affecting the open-circuit voltage, fill factor and short-circuit current of the bulk heterojunction polymer solar cells. So how to effectively control the micro-morphology of the bulk heterojunction is one of the key issues for improving the energy conversion efficiency of bulk heterojunction polymer solar cells. In this paper, the formation process of bulk heterojunction is introduced, and the micro-morphology control methods of bulk heterojunction developed in recent years are systematically summarized and discussed to provide guidance and reference for the preparation of the bulk heterojunction polymer solar cells.

Contents
1 Introduction
2 The formation process of organic bulk heterojunction
3 Regulation for micro-morphology of bulk heterojunction
3.1 Regulation for micro-morphology of bulk heterojunction by solvent-induced
3.2 Regulation for micro-morphology of bulk heterojunction by thermal annealing
3.3 Regulation for micro-morphology of bulk heterojunction by the ratio of donor and acceptor
4 Conclusion

Graphical abstract

关键词

体异质结 / 能量转换效率 / 太阳能电池 / 微观形貌

Key words

bulk heterojunction / energy conversion efficiency / solar cells / micro-morphology

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康建喜, 王世荣, 孙孟娜, 刘红丽, 李祥高. 体异质结型聚合物太阳能电池中的微观形貌调控方法[J]. 化学进展, 2017, 29(4): 400-411 DOI:10.7536/PC161213

Jianxi Kang, Shirong Wang, Mengna Sun, Hongli Liu, Xianggao Li. Regulation Methods for Micro-Morphology of Bulk Heterojunction Polymer Solar Cells[J]. Progress in Chemistry, 2017, 29(4): 400-411 DOI:10.7536/PC161213

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