肼硼烷的合成及产氢

张世亮; 姚淇露; 卢章辉*

doi:10.7536/PC161234

化学进展 ›› 2017, Vol. 29 ›› Issue (4) :426-434 DOI: 10.7536/PC161234

综述

扫码查看或转发全文

肼硼烷的合成及产氢

张世亮, 姚淇露, 卢章辉*

作者信息 +

Synthesis and Dehydrogenation of Hydrazine Borane

Shiliang Zhang, Qilu Yao, Zhanghui Lu*

Author information +

文章历史 +

摘要

肼硼烷（N₂H₄BH₃，HB）的含氢量高达15.4 wt%，易于制备，物理化学性质稳定，是一种极具潜力的化学储氢材料。肼硼烷可以通过热解、醇解和水解产氢。特别是，通过水解其硼烷基和选择性裂解肼基实现完全产氢后，其对应的N₂H₄BH₃-3H₂O系统的有效理论质量储氢容量达10 wt%，远高于已知的氢源系统NaBH₄-4H₂O（7.3 wt%），NH₃BH₃-4H₂O（5.9 wt%）和N₂H₄·H₂O（8.0 wt%）。合适的催化剂是促使肼硼烷完全产氢的关键。本文简要地介绍了肼硼烷的合成与表征，重点综述了温和条件下肼硼烷的硼烷基水解和肼基分解产氢所使用的催化体系及其催化性能，对肼硼烷完全产氢的机理进行分析，并对肼硼烷催化产氢的应用前景进行展望。

Abstract

Hydrazine borane (N₂H₄BH₃, HB) is considered as a highly promising hydrogen storage material due to its high hydrogen content (15.4 wt%), easy preparation, and good physical and chemical properties. Hydrogen can be produced from hydrazine borane via pyrolysis, methanolysis and hydrolysis reaction. Especially, a promising approach for complete hydrogen production from N₂H₄BH₃ is by hydrolysis of the BH₃ group and selective decomposition of the N₂H₄ moiety of N₂H₄BH₃, corresponding to a theoretical gravimetric hydrogen storage capacity (GHSC) of 10 wt% for the system N₂H₄BH₃-3H₂O. The GHSC of N₂H₄BH₃ is much higher than those of benchmark hydrogen storage systems NaBH₄-4H₂O (7.3 wt%), NH₃BH₃-4H₂O (5.9 wt%), and N₂H₄·H₂O (8.0 wt%). The suitable catalyst is essential for complete hydrogen generation from N₂H₄BH₃. In this paper, the synthesis and characterizations of hydrazine borane are briefly introduced. The developments of catalytic systems for hydrogen production from hydrolysis of the BH₃ group and dehydrogenation of the N₂H₄ moiety of hydrazine borane at mild conditions are significantly reviewed. Moreover, the mechanism of hydrogen production from hydrazine borane is concisely analyzed and the application prospects of hydrazine borane are also remarked in this review.

Contents
1 Introduction
2 Synthesis and characterization of hydrazine borane
2.1 Synthesis
2.2 Molecular and structural analyses
3 Dehydrogenation of hydrazine borane
3.1 Hydrolysis of the BH₃ group of hydrazine borane
3.2 Hydrolysis of the BH₃ group and dehydrogenation of the N₂H₄ moiety of hydrazine borane
3.3 Reaction mechanism of complete dehydrogenation of hydrazine borane
4 Conclusion

Graphical abstract

关键词

化学储氢材料 / 肼硼烷 / 产氢 / 催化剂

Key words

chemical hydrogen storage material / hydrazine borane / hydrogen production / catalyst

引用本文

引用格式 ▾

张世亮, 姚淇露, 卢章辉*. 肼硼烷的合成及产氢[J]. 化学进展, 2017, 29(4): 426-434 DOI:10.7536/PC161234

Shiliang Zhang, Qilu Yao, Zhanghui Lu*. Synthesis and Dehydrogenation of Hydrazine Borane[J]. Progress in Chemistry, 2017, 29(4): 426-434 DOI:10.7536/PC161234

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Schlapbach L, Züttel A. Nature, 2001, 414: 353.
[2] 张磊(Zhang L), 涂倩(Tu Q), 陈学年(Chen X N), 刘蒲(Liu P). 化学进展(Progress in Chemistry), 2014, 26(5): 749.
[3] Sartbaeva A, Kuznetsov V L, Wells S A, Edwards P P. Energy Environ. Sci., 2008, 1: 79.
[4] Ball M, Wietschel M. Int. J. Hydrogen Energy, 2009, 34: 615.
[5] Yang J, Sudik A, Wolverton C, Siegel D. Chem. Soc. Rev., 2010, 39: 656.
[6] Weidenthaler C, Felderhoff M. Energy Environ. Sci., 2011, 4: 2495.
[7] Dalebrook A F, Gan W J, Grasemann M, Moret S, Gabor L. Chem. Commun., 2013, 49: 8735.
[8] 徐东彦(Xu D Y), 张华民(Zhang H M), 叶威(Ye W). 化学进展(Progress in Chemistry), 2007, 19(10): 1599.
[9] Zahmakiran M, Özkar S. J. Mol. Catal. A: Chem., 2006, 258: 95.
[10] Marrero-Alfonso E Y, Gray J R, Davis T A, Matthews M A. Int. J. Hydrogen Energy, 2007, 32: 4723.
[11] 梁艳(Liang Y), 王平(Wang P), 戴洪斌(Dai H B). 化学进展(Progress in Chemistry), 2009, 21(10): 2220.
[12] Wang H X, Zhao Y R, Cheng F Y, Tao Z L, Chen J. Catal. Sci. Technol., 2016, 6: 3443.
[13] Yao Q L, Lu Z H, Jia Y S, Chen X S, Liu X. Int. J. Hydrogen Energy, 2015, 40: 2207.
[14] Hu Y J, Lu Z H, Wang Y Q, Chen X S, Xiong L H. Appl. Surf. Sci., 2015, 341: 185.
[15] Shen J, Yang L, Hu K, Luo W, Cheng G. Int. J. Hydrogen Energy, 2015, 40: 1062.
[16] Yao Q L, Shi W M, Feng G, Lu Z H, Zhang X L, Tao D J, Kong D J, Chen X S. J. Power Sources, 2014, 257: 293.
[17] Yang Y W, Feng G, Lu Z H, Hu N, Zhang F, Chen X S. Acta Phys. Chim. Sin., 2014, 30: 1180.
[18] Lu Z H, Li J P, Feng G, Yao Q L, Zhang F, Zhou R Y, Tao D J, Chen X S, Yu Z Q. Int. J. Hydrogen Energy, 2014, 39: 13389.
[19] Yao Q L, Shi Y, Zhang X L, Chen X S, Lu Z H. Chem. Asian J., 2016, 22: 3251.
[20] Chen W Y, Li D, Wang Z J, Qian G, Sui Z J, Duan X Z, Zhou X G, Yeboah I, Chen D. AIChE J., 2017, 63: 60.
[21] Yao Q L, Lu Z H, Wang Y Q, Chen X S, Feng G. J. Phys. Chem. C, 2015, 119: 14167.
[22] Yang Y W, Lu Z H, Hu Y J, Zhang Z J, Shi W M, Chen X S, Wang T T. RSC Adv., 2014, 4: 13749.
[23] Sanyal U, Demirci U B, Jagirdar B R, Miele P. ChemSusChem., 2011, 4: 1731.
[24] Li Z Y, Zhu G S, Lu G Q, Qiu S L, Yao X D. J. Am. Chem. Soc., 2010, 132: 1490.
[25] Yang Y W, Lu Z H, Chen X S. Mater. Technol., 2015, 30: 89.
[26] Xu Q, Chandra M. J. Power Sources, 2006. 163: 364.
[27] Yao Q L, Huang M, Lu Z H, Yang Y W, Zhang Y X, Chen X S, Yang Z. Dalton Trans., 2015, 44: 1070.
[28] Yao Q L, Lu Z H, Hu Y J, Chen X S. RSC Adv., 2016, 6: 89450.
[29] Akbayrak S, Tonbul Y, Özkar S. Appl. Catal. B: Environ., 2016, 198: 162.
[30] Yao Q L, Lu Z H, Huang W, Chen X S, Zhu J. J. Mater. Chem. A, 2016, 4: 8579.
[31] Lu Z H, Li J P, Zhu A L, Yao Q L, Huang W, Zhou R Y, Zhou R F, Chen X S. Int. J. Hydrogen Energy, 2013, 38: 5330.
[32] Singh S K, Singh A K, Aranishi K, Xu Q. J. Am. Chem. Soc., 2011, 133:19638.
[33] Song-II O, Yan J M, Wang H L, Wang Z L, Jiang Q. J. Power Sources, 2014, 262: 386.
[34] Chen J M, Yao Q L, Zhu J, Chen X S, Lu Z H. Int. J. Hydrogen Energy, 2016, 41: 3946.
[35] Wang J, Li W, Wen Y R, Gu L, Zhang Y. Adv. Energy Mater., 2015, 5: 1401879.
[36] Wang H L, Yan J M, Li S J, Zhang X W, Jiang Q. J. Mater. Chem. A, 2015, 3: 121.
[37] Moury R, Demirci U B. Energies, 2015, 8: 3118.
[38] Zhigach A F, Zakharov V V, Manelis G B, Nechiporenko G N, Nikitin V S, Esel’son B M. Zh. Neorg. Khim., 1973, 18: 1762.
[39] Hügle T, Kühnel M F, Lentz D. J. Am. Chem. Soc., 2009, 131: 7444.
[40] Zhong D C, Aranishi K, Singh A K. Demirci U B, Xu Q. Chem. Commun., 2012, 48: 11945.
[41] Goubeau V J, Ricker E Z. Anorg. Allg. Chem., 1961, 310:123.
[42] Gunderloy F C. US 3375087, 1968.
[43] Gunderloy F C. Inorg. Chem., 1963, 2: 221.
[44] Gunderloy F C. US 3159451, 1964.
[45] Uchida H S, Hefferan G T. US 3119652, 1964.
[46] Moury R, Moussa G, Demirci U B, Hannauer J, Bernard S, Petit E, Lee A, Miele P. Phys. Chem. Chem. Phys., 2012, 14: 1768.
[47] Mebs S, Grabowsky S, Förster D, Kickbusch R, Hartl M, Daemen L L, Morgenroth W, Luger P, Paulus B, Lentz D J. Phys.Chem. A, 2010, 114: 10185.
[48] Zhang Z J, Lu Z H, Chen X S. J. Mater. Chem. A, 2015, 3: 23520.
[49] Karahan S, Zahmakran M, Özkar S. Int. J. Hydrogen Energy, 2011, 36: 4958.
[50] Celik D, Karahan S, Zahmakiran M, Özkar S. Int. J. Hydrogen Energy, 2012, 37: 5143.
[51] Tunç N, Abay B, Rakap M. J. Power Sources, 2015, 299: 403.
[52] Yao Q L, Lu Z H, Yang K K, Chen X S, Zhu M H. Sci. Rep., 2015, 5: 15186.
[53] Sencanli S, Karahan S, Özkar S. Int. J. Hydrogen Energy, 2013, 38: 14693.
[54] Karahan S, Özkar S. Int. J. Hydrogen Energy, 2015, 40: 2255.
[55] Yao Q L, Lu Z H, Zhang Z J, Chen X S, Lan Y Q. Sci. Rep., 2014, 4: 7597.
[56] Yang K K, Yao Q L, Huang W, Chen X W, Lu Z H. Int. J. Hydrogen Energy, 2016, DOI: 10.1016/j.ijhydene.2016.12.029.
[57] Karahan S, Zahmakiran M, Özkar S. Dalton Trans., 2012, 41: 4912.
[58] Özhava D, K?l?caslan N Z, Özkar S. Appl. Catal. B: Environ., 2015, 162: 573.
[59] Singh S K, Xu Q. J. Am. Chem. Soc., 2009, 131:18032.
[60] He L, Huang Y, Wang A, Wang A, Chen X, Delgado J J, Zhang T. Angew. Chem., Int. Ed., 2012, 51: 6191.
[61] Yao Q L, Chen X S, Lu Z H. Energy Environ. Focus, 2014, 3: 236.
[62] Singh S K, Lu Z H, Xu Q. European J. Inorg. Chem., 2011, 14: 2232.
[63] Hannauer J, Akdim Q, Demirci U B, Geantet C, Herrmann J M, Miele P, Xu Q. Energ. Environ. Sci., 2011, 4: 3355.
[64] Hannauer J, Demirci U B, Geantet C, Herrmannb J M, Miele P. Int. J. Hydrogen Energy, 2012, 37: 10758.
[65] Aziza W B, Petit J F, Demirci U B, Xu Q, Miele P. Int. J. Hydrogen Energy, 2014, 39: 16919.
[66] Hannauer J, Akdim O, Demirci U B, Geantet C, Herrmann J M, Miele P, Xu Q. Int. J. Hydrogen Energy, 2012, 37: 9722.
[67] Li C M, Dou Y B, Liu J, Chen Y D, He S, Wei M, Evans D G, Duan X. Chem. Commun., 2013, 49: 9992.
[68] Clemençon D, Petit J F, Demirci U B, Xu Q, Miele P. J. Power Sources, 2014, 260: 77.
[69] Zhu Q L, Zhong D C, Demirci U B, Xu Q. ACS Catal., 2014, 4: 4261.
[70] Zhang Z J, Wang Y Q, Chen X S, Lu Z H. J. Power Sources, 2015, 291: 14.
[71] Zhang Z J, Lu Z H, Chen X S. ACS Sustain. Chem. Eng., 2015, 3: 1255.
[72] 卢章辉(Lu Z H), 张主军(Zhang Z J), 陈祥树(Chen X S). ZL 201410214740.9, 2017.
[73] 张主军(Zhang Z J). 江西师范大学硕士论文(Master Dissertation of Jiangxi Normal University), 2016.
[74] Chen J M, Lu Z H, Hang W, Kang Z B, Chen X S. J. Alloys Compd., 2017, 695: 3036.
[75] 贺艳斌(He Y B). 山西师范大学博士论文(Doctoral Dissertation of Shanxi Normal University), 2015.
[76] Block J, Schulz E G. J. Catal., 1973, 30: 327.
[77] Falconer J L, Wise H. J. Catal., 1976, 43: 220.
[78] 贺雷(He L), 黄延强(Huan Y Q), 王爱琴(Wang A Q), 王晓东(Wang X D), 张涛(Zhang T). 化工进展(Chemical Industry and Engineer Progress), 2014, 33(11): 2956.
[79] Lu Z H, Yao Q L, Zhang Z J, Yang Y W, Chen X S. J. Nanomater., 2014, 729029.
[80] Lu Z H, Xu Q. Funct. Mater. Lett., 2012, 5 (1): 1230001.