PM2.5中的有机硫酸酯类化合物

韩德文; 王鑫彤; 鞠法帅; 王杨君; 冯加良; 汪午

doi:10.7536/PC170118

化学进展 ›› 2017, Vol. 29 ›› Issue (5) :530-538 DOI: 10.7536/PC170118

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PM_2.5中的有机硫酸酯类化合物

^1*

作者信息 +

Organosulfates in PM_2.5

Dewen Han¹, Xintong Wang², Fashuai Ju¹, Yangjun Wang¹, Jialiang Feng¹, Wu Wang^1*

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摘要

有机硫酸酯是近年来新发现的二次有机气溶胶化合物，是大气PM_2.5的重要组分，是人为活动和生物排放的产物，不仅危害人体健康，还对全球气候产生影响。本文综述在不同大气环境下有机硫酸酯的种类结构，即：森林（清洁地区）以植被排放的异戊二烯和α-/β-蒎烯为前体物、城市（污染地区）以多环芳烃为前体物、受植被和人类活动共同影响的地区则以羰基化合物为前体物，与不同大气氧化剂在SO₂/H₂SO₄作用下形成有机硫酸酯的大气光化学过程；总结了到目前为止，有机硫酸酯类化合物在世界各地大气PM_2.5中的浓度水平；以及各技术手段在分析、检测有机硫酸酯类化合物时的优势和缺陷；讨论了影响有机硫酸酯形成的因素；提出了有机硫酸酯研究亟待解决的问题，并对未来研究方向进行了展望。

Abstract

Organosulfates which have been discovered in secondary organic aerosols are important constituents of PM_2.5 in the atmosphere. Formed through anthropogenic activities and biogenic emissions, they have negative impacts on not only human health but also global climate change. Based on major precursors in different atmospheric environments, i.e., biogenic volatile organic compounds isoprene and α-/β-pinene in forest (clean area), anthropogenic polycyclic aromatic hydrocarbons in urban (polluted area), and biogenic and anthropogenic mixed sources carbonyls in areas affected by both vegetation and human activities, we elaborated systematically the categories and structures of organosulfates and their photooxidation formation pathway under various atmospheric conditions with different atmospheric oxidants in the presence of SO₂/H₂SO₄. Then, relevant literatures have been reviewed as much as possible and the concentration levels in PM_2.5 in reported areas worldwide aresummarized. Moreover, up-to-date analytical techniques are described, as well as their benefits and drawbacks. Finally, impact factors of organosulfates formation are discussed. At the end of context, several issues are proposed which need to be addressed urgently, and future research directions in organosulfates are also prospected.
Contents
1 Introduction
2 The categories and formation mechanisms of OS
2.1 Forest (clean area)
2.2 Urban (polluted area)
2.3 Mixture areas affected by both vegetation and human activities
3 The concentration levels of OS
4 Analytical techniques
5 Impact factors
6 Conclusion

Graphical abstract

关键词

PM_2.5 / 有机硫酸酯类化合物 / 形成机理

Key words

PM_2.5 / organosulfates / formation mechanisms

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韩德文, 王鑫彤, 鞠法帅, 王杨君, 冯加良, 汪午. PM_2.5中的有机硫酸酯类化合物[J]. 化学进展, 2017, 29(5): 530-538 DOI:10.7536/PC170118

Dewen Han, Xintong Wang, Fashuai Ju, Yangjun Wang, Jialiang Feng, Wu Wang. Organosulfates in PM_2.5[J]. Progress in Chemistry, 2017, 29(5): 530-538 DOI:10.7536/PC170118

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