多孔材料基π络合吸附材料的合成及其应用

殷俞*; 张壮壮; 徐丹; 文志豪; 杨志峰; 袁爱华

doi:10.7536/PC170211

化学进展 ›› 2017, Vol. 29 ›› Issue (6) :628-636 DOI: 10.7536/PC170211

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多孔材料基π络合吸附材料的合成及其应用

殷俞*, 张壮壮, 徐丹, 文志豪, 杨志峰, 袁爱华

作者信息 +

π Complexation Adsorbents Based on Porous Materials:Preparation and Application

Yu Yin*, Zhuangzhuang Zhang, Dan Xu, Zhihao Wen, Zhifeng Yang, Aihua Yuan

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摘要

π络合吸附分离技术以低能耗、高效和可再生等优点，在燃料油的脱硫、烯烃/烷烃气体的分离、混合气体中CO的分离几个方面有广泛的应用。吸附材料是π络合吸附分离技术的关键。本文围绕π络合吸附材料的合成方法及应用效果，综述国内外的一些重要研究进展。总体来说，将过渡金属离子（Cu（Ⅰ）、Ag（Ⅰ）和Pd（Ⅱ）等）引入高比表面积的载体是合成π络合吸附材料的普遍方法。至今，基于无机分子筛合成π络合吸附材料的方法包括离子交换、浸渍、固相研磨和空间限域等。研究者在这方面开展了大量的工作，且卓有成效。近年，研究者致力基于金属有机框架（MOFs）合成π络合吸附材料，包括未修饰和修饰的MOFs，具备较好的研究和应用前景。此外，本文总结了目前几种π络合吸附材料的优缺点，并对未来发展趋势进行展望。

Abstract

π complexation techniques show the advantages of low energy consumption, high efficiency, and reproducibility, etc. Thus, the π complexation techniques have been widely used in the fields of fuel desulfurization, olefin/paraffin separation, and CO separation from gas mixtures. Adsorbents are the key factors to the π complexation techniques. This review focuses on the synthesis methods and application efficiency of the π complexation adsorbents, and summarizes some important advances both at home and abroad. In general, the universal methods to synthesize the π complexation adsorbents are introduction of transition metal ions (Cu(Ⅰ), Ag(Ⅰ), and Pd(Ⅱ), etc.) into the supports with high surface areas. So far, methods on preparation of π complexation adsorbents based on inorganic molecular sieves have been very detailed, including ion exchange, impregnation method, solid-state grinding, and space confining etc. In this respect, researchers have carried out a large amount of studies. Moreover, the adsorbents show high efficiency. Recently, researchers devote to preparation of π complexation adsorbents based on metal-organic frameworks (MOFs), including undecorated and decorated MOFs. This route has good prospects in research and application fields. In addition, this review summarizes the advantages and disadvantages of several π complexation adsorbents, and gives prospects for the future development trends.

Contents
1 Introduction
2 Preparation of π complexation adsorbents based on inorganic molecular sieves
2.1 Ion exchange method
2.2 Impregnation method
2.3 Solid-state grinding method
2.4 Space confining method
3 Preparation of π complexation adsorbents based on metal-organic frameworks (MOFs)
3.1 In situ π complexation adsorption sites
3.2 Construction of π complexation adsorption sites
4 Preparation of π complexation adsorbents based on other porous materials
5 Chemical theories of π complexation adsorption
6 Other applications of complexation effect
7 Conclusion and outlook

Graphical abstract

关键词

π络合 / 分子筛 / 金属有机框架(MOFs) / 吸附 / 选择性

Key words

π complexation / molecular sieve / metal-organic frameworks(MOFs) / adsorption / selectivity

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殷俞*, 张壮壮, 徐丹, 文志豪, 杨志峰, 袁爱华. 多孔材料基π络合吸附材料的合成及其应用[J]. 化学进展, 2017, 29(6): 628-636 DOI:10.7536/PC170211

Yu Yin*, Zhuangzhuang Zhang, Dan Xu, Zhihao Wen, Zhifeng Yang, Aihua Yuan. π Complexation Adsorbents Based on Porous Materials:Preparation and Application[J]. Progress in Chemistry, 2017, 29(6): 628-636 DOI:10.7536/PC170211

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