碳基纳米材料对水环境中放射性元素铀的吸附

梁宇, 顾鹏程, 姚文, 于淑君, 王建, 王祥科*

doi:10.7536/PC170427

化学进展 ›› 2017, Vol. 29 ›› Issue (9) :1062-1071 DOI: 10.7536/PC170427

综述

扫码查看或转发全文

碳基纳米材料对水环境中放射性元素铀的吸附

梁宇, 顾鹏程, 姚文, 于淑君, 王建, 王祥科*

作者信息 +

Adsorption of Radionuclide Uranium onto Carbon-Based Nanomaterials from Aqueous Systems

Yu Liang, Pengcheng Gu, Wen Yao, Shujun Yu, Jian Wang, Xiangke Wang*

Author information +

文章历史 +

摘要

放射性元素铀既是核燃料的主要成分又是核废料后期处理的关键元素，对环境造成潜在的污染，铀的污染治理研究对治理核污染有着重要的现实意义。本文针对碳纳米管、石墨烯以及其他碳基纳米材料对水体环境中放射性元素铀的吸附研究进行了概述和展望，包括碳基纳米材料的制备方法、去除效果和吸附机理。此外，针对纯碳材料对铀吸附量低等问题，提出并归纳了多种表面改性及复合方法。总之，制备高效低成本的碳基纳米吸附材料，提高碳基纳米材料对复杂条件下放射性元素的高效处理能力，将成为今后重点研究方向。

Abstract

With the development of nuclear technology, the radioactive nuclide pollution such as uranium pollution is threating the human health. Uranium is the major constituent of nuclear fuel and the key nuclide in spent fuel reprocessing. Carbon-based nanomaterials are promising for uranium removal due to their large specific surface area, excellent acid stability, higher radiation and thermal resistance. In this review, carbon-based nanomaterials such as carbon nanotubes, graphene and other carbon materials used as adsorbents for uranium removal have been summarized. The relevant synthetic methods, removal performance and adsorption mechanism are also discussed. And the adsorption performance of carbon-based materials can be improved by surface oxidization and physical or chemical modifications such as coating, grafting functional groups or molecules. However, the practical application of carbon-based nanomaterials has been limited because of their high cost and complicated synthesis process. Therefore, how to develop a low-cost, mature process technology and application system will be an important research direction in the future.
Contents
1 Introduction
2 The species of carbon-based nanomaterials
2.1 Carbon nanotubes
2.2 Graphene
2.3 Other carbon-based nanomaterials
3 Adsorption mechanism and influencing factors
4 Conclusion and outlook

Graphical abstract

关键词

碳基纳米材料 / 吸附 / 放射性元素 / 铀

Key words

carbon-based nanomaterials / adsorption / radionuclide / uranium

引用本文

引用格式 ▾

梁宇, 顾鹏程, 姚文, 于淑君, 王建, 王祥科*. 碳基纳米材料对水环境中放射性元素铀的吸附[J]. 化学进展, 2017, 29(9): 1062-1071 DOI:10.7536/PC170427

Yu Liang, Pengcheng Gu, Wen Yao, Shujun Yu, Jian Wang, Xiangke Wang*. Adsorption of Radionuclide Uranium onto Carbon-Based Nanomaterials from Aqueous Systems[J]. Progress in Chemistry, 2017, 29(9): 1062-1071 DOI:10.7536/PC170427

登录浏览全文

4963

注册一个新账户忘记密码

参考文献

原文顺序 | 出版日期 | 本文引用

[1] Xu Y C. Energy, 2008, 33(8):1197.
[2] Cao J J, Cohen A, Hansen J, Lester R, Peterson P, Xu H J. Science, 2016, 353(6299):547.
[3] Lenzen M. Energ. Convers. Manage., 2008, 49(8):2178.
[4] Shi W Q, Yuan L Y, Li Z J, Lan J H, Zhao Y L, Chai Z F. Radiochim. Acta, 2012, 100(8/9):727.
[5] Yu S J, Wang X X, Tan X L, Wang X K. Inorg. Chem. Front., 2015, 2(7):593.
[6] Ho J C, Lee C T P, Kao S F, Chen R Y, Ieong M C, Chang H L, Hsieh W H, Tzeng C C, Lu C F, Lin S L. Environ. Int., 2014, 73:295.
[7] Antunes S C, Pereira R, Marques S M, Castro B B, Gonçalves F. Sci. Total Environ., 2011, 410:87.
[8] Zhou S, Zhang X L. Energy, 2010, 35(11):4282.
[9] Zhang R, Chen C L, Li J, Wang X K. Appl. Surf. Sci., 2015, 349:129.
[10] Saïdou, Bochud F O, Baechler S, Moïse K N, Merlin N, Froidevaux P. Radiat. Meas., 2011, 46(2):254.
[11] Tang Y Z, Reeder R J. Geochim. Cosmochim. Acta, 2009, 73(10):2727.
[12] Donia A M, Atia A A, Moussa E M M, El-Sherif A M, Abd El-Magied M O. Hydrometallurgy, 2009, 95(3/4):183.
[13] Wang X X, Zhang S W, Li J X, Xu J Z, Wang X K. Inorg. Chem. Front., 2014, 1(8):641.
[14] Hoyer M, Zabelt D, Steudtner R, Brendler V, Haseneder R, Repke J U. Sep. Purif. Technol., 2014, 132:413.
[15] Liu X, Li J X, Wang X X, Chen C L, Wang X K. J. Nucl. Mater., 2015, 466:56.
[16] Shi W Q, Zhao Y L, Chai Z F. Prog. Chem., 2011, 23(7):1478.
[17] Bachmaf S, Merkel B J. Environ. Earth Sci., 2010, 63(5):925.
[18] Douglas G, Shackleton M, Woods P. Appl. Geochem., 2014, 42:27.
[19] Chouyyok W, Warner C L, Mackie K E, Warner M G, Gill G A, Addleman R S. Ind. Eng. Chem. Res., 2016, 55(15):4195.
[20] Wang Y L, Liu Z Y, Li Y X, Bai Z L, Liu W, Wang Y X, Xu X M, Xiao C L, Sheng D P, Diwu J, Su J, Chai Z F, E. Albrecht-Schmitt T, Wang S A. J. Am. Chem. Soc., 2015, 137(19):6144.
[21] Liu W, Dai X, Bai Z L, Wang Y L, Yang Z X, Zhang L J, Xu L, Chen L H, Li Y X, Gui D X, Diwu J, Wang J Q, Zhou R H, Chai Z F, Wang S A. Environ. Sci. Technol., 2017, 51:3911.
[22] Zheng T, Yang Z X, Gui D X, Liu Z Y, Wang X X, Dai X, Liu S T, Zhang L J, Gao Y, Chen L H, Sheng D P, Wang Y L, Diwu J, Wang J Q, Zhou R H, Chai Z F, E. Albrecht-Schmitt T, Wang S A. Nat. Commnun., 2017, 8:15369.
[23] Chen L H, Zheng T, Bao S S, Zhang L J, Liu H K, Zheng L M, Wang J Q, Wang Y X, Diwu J, Chai Z F, E. Albrecht-Schmitt T, Wang S A. Chem. -Eur. J., 2016, 22(34):11954.
[24] 盛国栋(Sheng G D), 杨世通(Yang S T), 郭志强(Guo Z Q), 孙玉兵(Sun Y B), 谭小丽(Tan X L), 陈长伦(Chen C L), 邵大冬(Shao D D), 王祥科(Wang X K). 核化学与放射化学(Journal of Nuclear and Radiochemistry), 2012, (06):321.
[25] Mauter M S, Elimelech M. Environ. Sci. Technol., 2008, 42(16):5843.
[26] Li Z J, Chen F, Yuan L Y, Liu Y L, Zhao Y L, Chai Z F, Shi W Q. Chem. Eng. J., 2012, 210:539.
[27] Fasfous I I, Dawoud J N. Appl. Surf. Sci., 2012, 259:433.
[28] Tian G, Geng J X, Jin Y D, Wang C L, Li S Q, Chen Z, Wang H, Zhao Y S, Li S J. J. Hazard. Mater., 2011, 190(1/3):442.
[29] 李兴亮(Li X L), 宋强(Song Q), 刘碧君(Liu B J), 刘春霞(Liu C X), 王航(Wang H), 耿俊霞(Geng J X), 陈震(Chen Z), 刘宁(Liu N), 李首建(Li S J). 化学进展(Progress in Chemistry), 2011, 7:1446.
[30] Chen J H, Lu D Q, Chen B, OuYang P K. J. Radioanal. Nucl. Chem., 2012, 295(3):2233.
[31] Song M M, Wang Q, Meng Y D. J. Radioanal. Nucl. Chem., 2012, 293(3):899.
[32] Lai Z J, Zhang Z B, Cao X H, Dai Y, Hua R, Le Z G, Luo M B, Liu Y H. J. Radioanal. Nucl. Chem., 2016, 310(3):1335.
[33] Ren X M, Chen C L, Nagatsu M, Wang X K. Chem. Eng. J., 2011, 170(2/3):395.
[34] Stafiej A, Pyrzynska K. Sep. Purif. Technol., 2007, 58(1):49.
[35] Tofighy M A, Mohammadi T. J. Hazard. Mater., 2011, 185(1):140.
[36] Li Y H, Wang S G, Zhang X F, Wei J Q, Xu C L, Luan Z K. Mater. Res. Bull., 2003, 38(3):469.
[37] Zhao G X, Li J X, Ren X M, Chen C L, Wang X K. Environ. Sci. Technol., 2011, 45(24):10454.
[38] Li J H, Li J Y, Meng H Y, Xie S Y, Zhang B W, Li L F, Ma H J, Zhang J Y, Yu M. J. Mater. Chem. A, 2014, 2(9):2934.
[39] Kim J H, Lee H I, Yeon J W, Jung Y, Kim J M. J. Radioanal. Nucl. Chem., 2010, 286(1):129.
[40] Li F Z, Li D M, Li X L, Liao J L, Li S J, Yang J J, Yang Y Y, Tang J, Liu N. Chem. Eng. J., 2016, 284:630.
[41] Kane C L, Mele E. Phys. Rev. Lett., 1997, 78(10):1932.
[42] Deng J J, You Y, Sahajwalla V, Joshi R K. Carbon, 2016, 96:105.
[43] Cho H G, Kim S W, Lim H J, Yun C H, Lee H S, Park C R. Carbon, 2009, 47(15):3544.
[44] Prasek J, Drbohlavova J, Chomoucka J, Hubalek J, Jasek O, Adam V, Kizek R. J. Mater. Chem., 2011, 21(40):15872.
[45] Sun Y B, Yang S T, Sheng G D, Guo Z Q, Wang X K. J. Environ. Radioact., 2012, 105:40.
[46] Shao D D, Hu J, Wang X K. Plasma Processes Polym., 2010, 7(12):977.
[47] Duan S X, Liu X, Wang Y N, Meng Y D, Alsaedi A, Hayat T, Li J X. Plasma Processes Polym., 2017, DOI:10.1002/ppap.201600218.
[48] Duan S X, Wang Y N, Liu X, Shao D D, Hayat T, Alsaedi A, Li J X. ACS Sustainable Chem. Eng., 2017, 5(5):4073.
[49] Wang X X, Fan Q H, Chen Z S, Wang Q, Li J X, Hobiny A, Alsaedi A, Wang X K. Chem. Rec., 2016, 16(1):295.
[50] Wang Y, Gu Z X, Yang J J, Liao J L, Yang Y Y, Liu N, Tang J. Appl. Surf. Sci., 2014, 320:10.
[51] Tan L C, Liu Q, Jing X Y, Liu J Y, Song D L, Hu S X, Liu L H, Wang J. Chem. Eng. J., 2015, 273:307.
[52] Mkhoyan K A, Contryman A W, Silcox J, Stewart D A, Eda G, Mattevi C, Miller S, Chhowalla M. Nano Lett., 2009, 9(3):1058.
[53] Kim K S, Zhao Y, Jang H, Lee S Y, Kim J M, Kim K S, Ahn J H, Kim P, Choi J Y, Hong B H. Nature, 2009, 457(7230):706.
[54] Geim A K. Science, 2009, 324(5934):1530.
[55] Kostarelos K, Novoselov K S. Science, 2014, 344(6181):261.
[56] Machado B F, Serp P. Catal. Sci. Technol., 2012, 2(1):54.
[57] Chabot V, Higgins D, Yu A P, Xiao X C, Chen Z W, Zhang J J. Energ. Environ. Sci., 2014, 7(5):1564.
[58] Yi M, Shen Z G. J. Mater. Chem. A, 2015, 3(22):11700.
[59] Park S, An J, Piner R D, Jung I, Yang D, Velamakanni A, Nguyen S T, Ruoff R S. Chem. Mater., 2008, 20(21):6592.
[60] Obraztsov A N. Nat. Nanotechnol., 2009, 4(4):212.
[61] Wei Z Q, Wang D B, Kim S, Kim S Y, Hu Y K, Yakes M K, Laracuente A R, Dai Z, Marder S R, Berger C. Science, 2010, 328(5984):1373.
[62] Brodie B C. Philosophical Transactions of the Royal Society of London, 1859, 149:249.
[63] Staudenmaier L. Eur. J. Inorg. Chem., 1898, 31(2):1481.
[64] Hummers Jr W S, Offeman R E. J. Am. Chem. Soc., 1958, 80(6):1339.
[65] Wang S B, Sun H Q, Ang H M, Tadé M O. Chem. Eng. J., 2013, 226:336.
[66] Loh K P, Bao Q L, Ang P K, Yang J. J. Mater. Chem., 2010, 20(12):2277.
[67] Wang Y N, Liu X, Huang Y X, Hayat T, Alsaedi A, Li J X. J. Radioanal. Nucl. Chem., 2017, 311(1):209.
[68] Liu X, Wang X X, Li J X, Wang X K. Sci. China Chem., 2016, 59(7):869.
[69] Chen X, Wang X L, Wang S W, Qi J S, Xie K, Liu X, Li J X. Arab. J. Chem., 2016, DOI:org/10.1016/j.arabjc.2016.06.009.
[70] Zhao Z W, Li J X, Wen T, Shen C C, Wang X K, Xu A W. Colloids Surf. A Physicochem. Eng. Asp., 2015, 482:258.
[71] Shao D D, Hou G S, Li J X, Wen T, Ren X M, Wang X K. Chem. Eng. J., 2014, 255:604.
[72] Liu X, Huang Y S, Duan S X, Wang Y N, Li J X, Chen Y T, Hayat T, Wang X K. Chem. Eng. J., 2016, 302:763.
[73] Zhao G X, Wen T, Yang X, Yang S B, Liao J L, Hu J, Shao D D, Wang X K. Dalton Trans., 2012, 41(20):6182.
[74] Zhang Z B, Qiu Y F, Dai Y, Wang P F, Gao B, Dong Z M, Cao X H, Liu Y H, Le Z G. J. Radioanal. Nucl. Chem., 2016, 310(2):547.
[75] Song W C, Wang X X, Wang Q, Shao D D, Wang X K. Phys. Chem. Chem. Phys., 2015, 17(1):398.
[76] Cheng H X, Zeng K F, Yu J T. J. Radioanal. Nucl. Chem., 2013, 298(1):599.
[77] Chen S P, Hong J X, Yang H X, Yang J Z. J. Environ. Radioact., 2013, 126:253.
[78] Tan L C, Wang Y, Liu Q L, Wang J, Jing X Y, Liu L H, Liu J Y, Song D L. Chem. Eng. J., 2015, 259:752.
[79] Zhao Y G, Li J X, Zhang S W, Chen H, Shao D D. RSC Adv., 2013, 3(41):18952.
[80] Duan S X, Liu X, Wang Y N, Shao D D, Alharbic N S, Alsaedic A, Li J X. J. Taiwan Inst. Chem. Eng., 2016, 65:367.
[81] Duan S X, Li J X, Liu X, Wang Y N, Zeng S Y, Shao D D, Hayat T. ACS Sustainable Chem. Eng., 2016, 4(6):3368.
[82] Chen L, Zhao D L, Chen S H, Wang X B, Chen C L. J. Colloid Interface Sci., 2016, 472:99.
[83] Tan L C, Wang J, Liu Q, Sun Y B, Jing X, Liu L Y, Liu J H, Song D L. New J. Chem., 2015, 39(2):868.
[84] Gao J K, Hou L A, Zhang G H, Gu P. J. Hazard. Mater., 2015, 286:325.
[85] Liang C D, Li Z J, Dai S. Angew. Chem. Int. Ed., 2008, 47(20):3696.
[86] Wang Y Q, Zhang Z B, Liu Y H, Cao X H, Liu Y T, Li Q. Chem. Eng. J., 2012, 198/199:246.
[87] Cai H M, Lin X Y, Qin Y, Luo X G. J. Radioanal. Nucl. Chem., 2016, 311(1):695.
[88] Wen T, Wang X X, Wang J, Chen Z S, Li J X, Hu J, Hayat T, Alsaedi A, Grambow B, Wang X K. Inorg. Chem. Front., 2016, 3(10):1227.
[89] Sun Y B, Yang S B, Chen Y, Ding C C, Cheng W C, Wang X K. Environ. Sci. Technol., 2015, 49(7):4255.
[90] Wang X X, Fan Q H, Yu S J, Chen Z S, Ai Y J, Sun Y B, Hobiny A, Alsaedi A, Wang X K. Chem. Eng. J., 2016, 287:448.
[91] 杜毅(Du Y), 王建(Wang J), 王宏青(Wang H Q), 夏良树(Xia L S),王祥科(Wang X K). 农业环境科学学报(Journal of Agro-Environment Science), 2016, (10):1837.
[92] 王祥学(Wang X X), 李洁(Li J), 于淑君(Yu S J),张瑞(Zhang R), 李家星(Li J X), 王祥科(Wang X K). 核化学与放射化学(Journal of Nuclear and Radiochemistry), 2015, (05):329.