石墨烯基分离膜研究进展

万武波; 纪冉; 何锋*

doi:10.7536/PC170501

化学进展 ›› 2017, Vol. 29 ›› Issue (8) :833-845 DOI: 10.7536/PC170501

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石墨烯基分离膜研究进展

万武波, 纪冉, 何锋*

作者信息 +

Recent Advances in Graphene Based Separation Membranes

Feng He, Ran Ji, Feng He*

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摘要

石墨烯为单层平面碳原子以sp²杂化方式紧密结合在一起形成的二维原子晶体，可作为基本材料构筑各种不同性能的宏观二维分离膜，是目前膜分离研究领域的一颗崭亮新星。本文重点介绍了各种石墨烯基分离膜的制备方法，并对其在水处理、气体分离、海水淡化等方向的应用研究进行评述。相比于传统高分子基分离膜，石墨烯分离膜在抗污染性能、膜通量以及选择性方面均有提升。除此之外，本文对基于其他新兴二维材料——氮化硼（BN）、二硫化钼（MoS₂）以及二硫化钨（WS₂）等的分离膜研究也进行了前瞻性讨论。最后，对石墨烯基膜的应用机遇和挑战作出评价，同时对其发展前景作出展望。

Abstract

Graphene is a one-atom-thick planar sheet of sp²-bonded carbon atoms that are densely packed in a two-dimensional crystal. As the building block for various macroscopic membranes, graphene has been known as a rising star in the area of membrane separation. The preparation and application of graphene based separation membrane are discussed in this review. Particular emphasis is directed to the wide application of graphene based membrane in the field of water treatment, gas separation, desalination and so on. Compared to traditional polymer membrane, graphene based separation membrane has the advantage of anti-fouling, high flux and good selectivity. Moreover, the application of other emerging 2D materials such as BN, MoS₂ and WS₂ in separation technology is also discussed. Finally, the future opportunities and challenges for the wide application of graphene based membrane are also discussed along with perspectives for future research in these fields.
Contents
1 Introduction
2 The preparation of graphene based membranes
2.1 Vacuum filtration method
2.2 Spin coating/spraying method
2.3 Layer-by-layer self-assembly method
2.4 Blending method
3 The application of graphene based membranes
3.1 Gas separation
3.2 CO₂ capture
3.3 Water purification
3.4 Desalination
3.5 Isotope removal
4 Membrane modification and performance improvement
4.1 Antifouling properties
4.2 Flux increase
4.3 Balance between the selectivity and flux
5 Separation membranes based on other emerging two-dimensional materials
6 Conclusion

Graphical abstract

关键词

石墨烯 / 氧化石墨烯 / 膜 / 复合材料 / 分离

Key words

graphene / graphene oxide / membrane / composites / separation

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万武波, 纪冉, 何锋*. 石墨烯基分离膜研究进展[J]. 化学进展, 2017, 29(8): 833-845 DOI:10.7536/PC170501

Feng He, Ran Ji, Feng He*. Recent Advances in Graphene Based Separation Membranes[J]. Progress in Chemistry, 2017, 29(8): 833-845 DOI:10.7536/PC170501

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