动态可逆作用是构筑智能材料体系,实现材料性能可控、可调性的重要工具。但是,多数基于动态可逆作用的智能体系仅能对"开/关"转换的外界刺激因素,如光、热、溶剂、pH等产生响应,不能实现自动调控。化学振荡反应及自振荡高分子材料的发展为新型自调控智能体系的构建提供了重要的思路。本文结合自调控智能体系的最新研究进展,介绍化学振荡反应调控的动态可逆智能体系(DRIS),包括利用动态共价键、主-客体作用、配位作用、离子作用、分子间作用等动态可逆作用构筑的纳米粒子自动聚集/分散体系、两亲性分子自组装/解组装体系、宏观凝胶自组装/解组装体系、自动分子器件、自动荧光振荡体系等。最后,对化学振荡反应调控的动态可逆智能体系的研究与发展进行展望。
Dynamic and reversible interaction is one of important tools for constructing intelligent material systems with controllability and adjustability. However, most of the intelligent systems based on dynamic and reversible interactions only respond to "on/off" transition of external stimuli, including light, heat, solvent, pH, etc., instead of automatic regulation. The development of chemical oscillating reactions and self-oscillating polymer materials provides an important idea for the construction of self-regulated intelligent systems. We introduce dynamic and reversible intelligent systems (DRIS) regulated by chemical oscillating reactions, including autonomous aggregation/disaggregation nanoparticle systems, autonomous assembly/disassembly amphiphilic molecule systems, autonomous assembly/disassembly hydrogel systems, autonomous molecular shuttle systems and autonomous fluorescent oscillation systems, which are constructed base on dynamic and reversible interactions, such as dynamic covalent bonds, host-guest interactions, coordination interactions, ionic interactions and intermolecular interactions. Finally, we prospect the future investigation and development of DRIS regulated by chemical oscillating reactions.
Contents
1 Introduction
2 Chemical oscillating reactions
3 General construction mechanism for DRIS
4 DRIS based on different dynamic and reversible interactions
4.1 DRIS based on dynamic covalent bonds
4.2 DRIS based on host-guest interactions
4.3 DRIS based on coordination interactions
4.4 DRIS based on ionic interactions
4.5 DRIS based on intermolecular interactions
5 Conclusion and outlook
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