纳米NCS在电化学能量转换和储存中的制备和应用

朱永明, 姜云鹏, 胡会利*

doi:10.7536/PC170560

化学进展 ›› 2017, Vol. 29 ›› Issue (11) :1422-1434 DOI: 10.7536/PC170560

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纳米NCS在电化学能量转换和储存中的制备和应用

朱永明, 姜云鹏, 胡会利*

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Preparation and Application of Nanometer NCS in Electrochemical Energy Conversion and Storage

Yongming Zhu, Yunpeng Jiang, Huili Hu*

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摘要

镍-钴双金属硫化物（NiCo₂S₄）具有典型的AB₂O₄尖晶石结构，NiCo₂S₄的电导率比NiCo₂O₄电导率高两个数量级，在室温下的电导率高达1.25×10⁶S·m^-1。此外，NiCo₂S₄可提供比相应的单组分硫化物更有效的氧化还原反应，由于其独特的纳米结构和电化学性能，具有很大的应用潜力。本文系统地综述了不同结构纳米NiCo₂S₄的制备及其在电化学能量转换和储存中的应用，介绍了NiCo₂S₄纳米材料的形貌特征、物化特性以及合成方法。预处理条件、制备方法和生长基体都会对NiCo₂S₄纳米结构的形貌和性能产生影响，不同纳米结构（如纳米针、纳米线、纳米棒、纳米管、纳米盒、纳米片、纳米板和层次结构）的NiCo₂S₄可通过多种方法制得（如水热法和溶剂热法、低温合成法、阴离子交换法、蒸气转换法、电沉积方法、共沉淀法和自组装等），其中最常用的是水热和溶剂热法，因为它们成本低、易于处理且适合大规模制造。同时，总结了NiCo₂S₄纳米材料在电催化、超级电容器和锂离子电池领域中的应用现状；分析和比较其不同纳米结构的制备工艺、方法和应用，希望能促进NiCo₂S₄纳米材料在电化学能量转换和储存领域的发展；最后提出NiCo₂S₄纳米材料的发展及应用方向。

Abstract

Nickel-cobalt bimetallic sulfide (NiCo₂S₄) has a typical AB₂O₄ spinel structure. The conductivity of NiCo₂S₄ is two orders of magnitude higher than that of NiCo₂O₄, and its conductivity is 1.25×10⁶S·m^-1at room temperature. In addition, NiCo₂S₄ provides a more efficient redox reaction than the corresponding one-component sulfide, and has great potential for its unique nanostructures and electrochemical properties. In this paper, the preparation of NiCo₂S₄ nanostructures and its application in electrochemical energy conversion and storage are reviewed. The morphology, physicochemical properties and synthesis methods of NiCo₂S₄ nano materials are introduced. Pretreatment conditions, preparation methods and growth matrix will have an effect on the morphology and properties of NiCo₂S₄ nanostructures. NiCo₂S₄ with different nanostructures (such as nanoneedles, nanowires, nanorods, nanotubes, nanocapses, nanosheets, nanostructures and hierarchical structures) can be prepared by a variety of methods (such as hydrothermal method and solvent heat method, low temperature synthesis method, anion exchange method, steam conversion method, electrodeposition method, coprecipitation method and self-assembly, etc.). Among them, hydrothermal and solvothermal are the most commonly used methods because they have the characteristics of low cost, easy handling and suitable for large scale manufacturing. The application status of NiCo₂S₄ nano materials in electrocatalysis, supercapacitors and lithium ion batteries is summarized. This paper analyzes and compares the preparation process, method and application of different nanostructures, hoping to promote the development of NiCo₂S₄ nano materials in the field of electrochemical energy conversion and storage. The development and application direction of NiCo₂S₄ nano materials are proposed.
Contents
1 Introduction
2 Preparation of NiCo₂S₄ nanostructures
3 Electrochemical application of NiCo₂S₄ nanostructures
3.1 Electrochemical catalysis:bifunctional electrocatalysts
3.2 Pseudocapacitive properties:supercapacitors
3.3 New electrode materials:anode material for Li-ion batteries
4 Conclusion

关键词

NiCo₂S₄ / 电极材料 / 形貌与性质 / 制备

Key words

NiCo₂S₄ / electrode materials / morphology and properties / preparation

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朱永明, 姜云鹏, 胡会利*. 纳米NCS在电化学能量转换和储存中的制备和应用[J]. 化学进展, 2017, 29(11): 1422-1434 DOI:10.7536/PC170560

Yongming Zhu, Yunpeng Jiang, Huili Hu*. Preparation and Application of Nanometer NCS in Electrochemical Energy Conversion and Storage[J]. Progress in Chemistry, 2017, 29(11): 1422-1434 DOI:10.7536/PC170560

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Received	Published	Revised
2017-05-27	2017-11-15	2017-09-18
Online Date
2017-10-27

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