水体中重金属污染物锑因为具有较高的积累毒性和致癌性而受到研究者的广泛关注。近年来由于世界范围内的锑污染问题日益严峻，因此急需发展经济高效的锑污染处理技术。纳米Fe0、Fe3O4以及FeMnOx等铁基复合材料凭借其吸附能力强，易分离回收以及安全环保等特点而成为国内外锑污染去除领域的研究热点。本文总结了零价铁和铁氧化物复合材料以及铁基双金属氧化物的制备、改性方法及其对水中污染物锑的去除，重点分析了不同铁基复合材料对Sb（Ⅲ）和Sb（Ⅴ）的吸附机理，总结了温度、pH、共存离子等外界环境对铁基复合材料吸附性能的影响机制，优选了最佳的吸附条件。最后介绍了现有锑污染去除研究中存在的主要问题，展望了铁基复合材料处理水中锑污染物的重点发展方向。
The pollution of antimony (Sb) species in natural waters has drawn more and more attention due to their high cumulative toxicity and carcinogenicity. In recent years, it is highly in demand to develop efficient and economical technologies to address the increasing pollution of antimony all over the world. Iron-based composite materials (e.g. Fe0, Fe3O4, and FeMnOx) have become a research hotspot in the field of antimony treatment based on their various advantages, including high adsorption capacity, easy separation and recycling, safety and environmental friendliness, etc. This article summarizes the preparation, modification and application of iron-based composite materials based on zero-valent iron, ferric oxide and iron bimetallic oxide for the removal of Sb(Ⅲ) and Sb(Ⅴ) in water. The adsorption mechanisms of Sb(Ⅲ) and Sb(Ⅴ) by different iron-based composite materials are emphatically discussed. The effects of temperature, pH and co-existing ions on the Sb adsorption of iron-based composite materials are also investigated, to find the optimal adsorption condition. Finally, some primary issues about antimony removal are proposed and the outlook of key developing trends on the antimony removal by iron-based composite materials are presented.
Contents
1 Introduction
2 The removal of Sb by zero-valent iron based composite materials
2.1 The physical modification of nano-Fe0
2.2 The loading modification of nano-Fe0
2.3 The stabilization modification of nano-Fe0
3 The removal of Sb by ferric oxide based composite materials
3.1 The composite materials based on magnetic Fe3O4
3.2 The composite materials based on ferric oxide hydrate
4 The removal of Sb by iron bimetallic oxide based composite materials
4.1 Iron and manganese oxides
4.2 Other iron bimetallic oxides
5 Conclusion
[1] 宁增平(Ning Z P), 肖唐付(Xiao T F). 地球与环境(Earth and Environment), 2007, 35(2):176.
[2] 卿仔轩(Qing Z X). 湖南有色金属(Hunan Nonferrous Metals), 2012, 28(2):71.
[3] Filella M, Belzile N, Chen Y W. Cheminform, 2003, 34(23):125.
[4] Smithsimon C. ATSDR's Toxicological Profiles on CD-ROM. Version 5. Crc Press, 2002. 26.
[5] 谢李娜(Xie L N), 周建伟(Zhou J W), 郝春明(Hao C M), 刘慧林(Liu H L), Nyirenda M T, 鲁槚银(Lu J Y), 李立刚(Li L G), 朱越(Zhu Y). 地质科技情报(Geological Science and Technology Information), 2016, 35(2):197.
[6] Fu Z Y, Wu F C, Amarasiriwardena D, Mo C, Liu B J, Zhu J, Deng Q J, Liao H Q. Sci. Total Environ., 2010, 408(16):3403.
[7] Nyirenda M T. 中国地质大学博士论文(Doctoral Dissertation of China University of Geosciences), 2016.
[8] 党永锋(Dang Y F), 赵彦龙(Zhao Y L), 邓锐(Deng R), 梁永津(Liang Y J). 广东微量元素科学(Guangdong Trace Elements Science), 2016, 23(6):12.
[9] 张晓健(Zhang X J). 给水排水(Water & Wastewater Engineering), 2016, 42(10):9.
[10] Hiller E, Lalinská B, Chovan M, Jurkovi? L', Klimko T, Jankulár M, Hovori? R, Šottník P, Fl'aková R, ?enišová Z. Appl. Geochem., 2012, 27(3):598.
[11] Ritchie V J, Ilgen A G, Mueller S H, Trainor T P, Goldfarb R J. Chem. Geol., 2013, 335:172.
[12] 黄艳超(Hang Y C), 武雪芳(Wu X F), 周羽化(Zhou Y H), 卢延娜(Lu Y N), 王宗爽(Wang Z S). 南京师范大学学报(自然科学版) (Journal of Nanjing Normal University(Natural Science Edition)), 2015, 38(4):122.
[13] 王华伟(Wang H W), 李晓月(Li X Y), 李卫华(Li W H), 孙英杰(Sun Y J). 环境科学(Environmental Science), 2017, (1):180.
[14] 聂孝红(Nie X H), 尹昊(Yin H), 郭东矗(Guo D C), 国辉(Guo H), 周金星(Zhou J X), 彭霞薇(Peng X W). 生态学杂志(Chinese Journal of Ecology), 2017, 36(6):1658.
[15] Zhou Z, Dai C M, Zhou X F, Zhao J F, Zhang Y L. Water Air Soil Pollut., 2015, 226(3):76.
[16] Saeidnia S, Asadollahfardi G, Darban A K. Desalin. Water Treat., 2016, 57(47):22321.
[17] Dai C M, Zhou Z, Zhou X F, Zhang Y L. Water Air Soil Pollut., 2013, 225(1):1799.
[18] Li J L, Bao H L, Xiong X M, Sun Y K, Guan X H. Sep. Purif. Technol., 2015, 151:276.
[19] Liang L P, Sun W, Guan X H, Huang Y Y, Choi W Y, Bao H L, Li L, Jiang Z. Water Res., 2014, 49(1):371.
[20] Matos C F, Galembeck F, Zarbin A J G. Carbon, 2012, 50(12):4685.
[21] 陈春宁(Chen C N), 石林(Shi L), 熊正为(Xiong Z W), 刘金香(Liu J X), 何少华(He S H), 谢永波(Xie Y B). 安全与环境学报(Journal of Safety and Environment), 2007, 7(4):46.
[22] Xu C H, Zhang B L, Zhu L J, Lin S, Sun X P, Jiang Z, Tratnyek P G. Environ. Sci. Technol., 2016, 50(3):1483.
[23] Zhao X Q, Dou X M, Mohan D, Pittman C U J, Yong S O, Jin X. Chem. Eng. J., 2014, 247(7):250.
[24] Mishra S, Dwivedi J, Kumar A, Sankararamakrishnan N. RSC Adv., 2016, 6(98):95865.
[25] 胡志勇(Hu Z Y), 何少华(He S H), 尹萌(Yin M), 谷志攀(Gu Z P). 矿业工程(Mining Engineering), 2007, 5(3):60.
[26] Xi J H, He M C, Lin C Y. Environ. Earth Sci., 2010, 60(4):715.
[27] Saeidnia S, Asadollahfardi G, Darban A K, Mohseni M. Water Sci. Technol., 2016, 73(10):2493.
[28] 李佳佳(Li J J). 昆明理工大学硕士论文(Master Dissertation of Kunming University of Science and Technology), 2014.
[29] 金旭(Jin X), 游少鸿(You S H), 林华(Lin H), 乔建(Qiao J), 杨明匀(Yang M Y), 何昌杰(He C J). 工业安全与环保(Industrial Safety and Environmental Protection), 2016, 42(2):29.
[30] Akarsu B. Master Dissertation of I · zmir Institute of Technology, 2013.
[31] 傅晓艳(Fu X Y), 鲍建国(Bao J G), 杜江坤(Du J K), 周雨(Zhou Y). 安全与环境工程(Safety and Environmental Engineering), 2015, 22(6):51.
[32] Shi Z Q, Fan D M, Johnson R L, Tratnyek P G, Nurmi J T, Wu Y X, Williams K H. J. Contam. Hydrol., 2015, 181:17.
[33] Tosco T, Papini M P, Viggi C C, Sethi R. Journal of Cleaner Production, 2014, 77:10.
[34] Hasany S M, Chaudhary M H. Appl. Radiat. Isot., 1996, 47(4):467.
[35] Sudarsan V, Muthe K P, Vyas J C, Kulshreshtha S K. J. Alloys Compd., 2002, 336(1/2):119.
[36] 周哲(Zhou Z). 同济大学硕士论文(Master Dissertation of Tongji University), 2015.
[37] 何娴(He X). 中国地质大学(北京)硕士论文(Master Dissertation of China University of Geosciences (Beijing)), 2014.
[38] 吕双(Lv S). 青岛科技大学硕士论文(Master Dissertation of Qingdao University of Science and Technology), 2016.
[39] 谭丽莎(Tan L S), 孙明洋(Sun M Y), 胡运俊(Hu Y J), 程丽华(Cheng L H), 徐新华(Xu X H). 化学进展(Progess in Chemistry), 2013, 12:2147.
[40] 杨秀贞(Yang X Z). 湖南大学博士论文(Doctoral Dissertation of Hunan University), 2015.
[41] 高冬兰(Gao D L). 南京理工大学硕士论文(Master Dissertation of Nanjing University of Science and Technology), 2013.
[42] Zhu K C, Duan Y Y, Wang F, Gao P, Jia H Z, Ma C Y, Wang C Y. Chem. Eng. J., 2017, 311(3):236.
[43] 傅毛生(Fu M S), 许龙飞(Xu L F), 钟学明(Zhong X M), 谢宇(Xie Y). 化学研究与应用(Chemical Research and Application), 2013, 25(4):554.
[44] 周利民(Zhou L M), 王一平(Wang Y P), 刘峙嵘(Liu Z R), 黄群武(Huang Q W). 物理化学学报(Acta Physico-Chimica Sinica), 2006, 22(11):1342.
[45] Qi Z L, Joshi T P, Liu R P, Liu H J, Qu J H. J. Hazard. Mater., 2017, 329:193.
[46] Chmielewská E, Tylus W, Drábik M, Majzlan J, Krav? ak J, Williams C, ?aplovi? ová M, ?aplovi? L'. Microporous Mesoporous Mater., 2017, 248:222.
[47] Qi P F, Pichler T. J. Hazard. Mater.,2017, 330:142.
[48] Leuz A K, M nch H, Johnson C A. Environ. Sci. Technol., 2006, 40(23):7277.
[49] Iram M, Guo C, Guan Y P, Ishfaq A, Liu H Z. J. Hazard. Mater., 2010, 181(1):1039.
[50] Teja A S, Koh P Y. Prog. Cryst. Growth Charact. Mater., 2009, 55(1/2):22.
[51] Shan C, Ma Z Y, Tong M P. J. Hazard. Mater., 2014, 268(3):229.
[52] Wang Y K, Liang Y, Jiao L, Du D M, Xu J X. Chem. Eng. J., 2012, 211/212(47):406.
[53] Xi J H, He M C, Wang K P, Zhang G Z. J. Geochem. Explor., 2013, 132(3):201.
[54] Salam M A, Mohamed R M. Chem. Eng. Res. Des., 2013, 91(7):1352.
[55] Zhang W M, Wu X L, Hu J S, Guo Y G, Wan L J. Adv. Funct. Mater., 2010, 18(24):3941.
[56] Yang X Z, Zhou S, Liu L X. Chem. Eng. J., 2015, 260:444.
[57] Li P, Chen Y J, Hu X, Lian H Z. Talanta, 2015, 134:292.
[58] Sun S H, Zeng H, Robinson D B, Raoux S, Rice P M, Wang S X, Li G X. J. Am. Chem. Soc., 2004, 126(1):273.
[59] Qi Z L, Lan H C, Joshi T P, Liu R P, Liu H J, Qu J H. RSC Adv., 2016, 6(71):66990.
[60] Meng S, Liu H, Yang C H, Yu W, Hou D L. Appl. Surf. Sci., 2012, 258(10):4449.
[61] Tiberg C, Sj stedt C, Persson I, Gustafsson J P. Geochim. Cosmochim. Acta, 2013, 120(120):140.
[62] Mitsunobu S, Takahashi Y, Terada Y, Sakata M. Environ. Sci. Technol., 2010, 44(10):3712.
[63] Qi P F, Pichler T. Chemosphere, 2016, 145:55.
[64] Baltpurvins K A, Burns R C, Lawrance G A, Stuart A D. Environ. Sci. Technol., 1996, 30(3):939.
[65] 潘丙军(Pan B J). 南京大学博士论文(Doctoral Dissertation of Nanjing University), 2010.
[66] 许光眉(Xu G M). 湖南大学博士论文(Doctoral Dissertation of Hunan University), 2006.
[67] 许光眉(Xu G M), 施周(Shi Z), 邓军(Deng J). 环境化学(Environmental Chemistry), 2006, 25(4):481.
[68] Miao Y Y, Han F C, Pan B C, Niu Y J, Nie G Z, Lv L. J. Environ. Sci., 2014, 26(2):307.
[69] 缪阳洋(Miao Y Y). 南京大学硕士论文(Master Dissertation of Nanjing University), 2013.
[70] Biswas B K, Inoue J I, Kawakita H, Ohto K, Inoue K. J. Hazard. Mater., 2009, 172(2/3):721.
[71] 朱瑾(Zhu J), 楼子墨(Lou Z M), 王卓行(Wang Z H), 徐新华(Xu X H). 化学进展(Progress in Chemistry), 2014, 26(9):1551.
[72] 叶鸣(Ye M), 曾嵘(Zeng R), 张先斌(Zhang X B), 李丽(Li L). 广东化工(Guangdong Chemical Industry), 2013, 40(16):44.
[73] 邹卫华(Zou W). 湖南大学博士论文(Doctoral Dissertation of Hunan University), 2006.
[74] 王向琴(Wang X Q). 北京师范大学博士论文(Doctoral Dissertation of Beijing Normal University), 2011.
[75] 曾嵘(Zeng R). 昆明理工大学硕士论文(Master Dissertation of Kunming University of Science and Technology), 2013.
[76] Xu W, Wang H J, Liu R P, Zhao X, Qu J H. J. Colloid Interface Sci., 2011, 363(1):320.
[77] 徐伟(Xu W), 刘锐平(Liu R P), 曲久辉(Qu J H), 彭若梦(Peng R M). 环境科学学报(Acta Scientiae Circumstantiae), 2012, 32(2):270.
[78] Liu R P, Liu F, Hu C Z, He Z, Liu H J, Qu J H. J. Hazard. Mater., 2015, 300:847.
[79] Liu R P, Xu W, He Z, Lan H C, Liu H J, Qu J H, Prasai T. Chemosphere, 2015, 138:616.
[80] Bai Y H, Jefferson W A, Liang J S, Yang T T, Qu J H. J. Environ. Sci., 2016, 54:126.
[81] Cao D, Zeng H B, Yang B, Zhao X. J. Hazard. Mater., 2017, 336:33.
[82] Li Y C, Zhang F, Hu X X, Ren B Z. American Chemical Science Journal, 2016, 14(2):1.
[83] 胡晓先(Hu X X). 湖南科技大学硕士论文(Master Dissertation of Hunan University of Science and Technology), 2016.
[84] Li Y C, Hu X X, Ren B Z, Yue J, Yang W C. Desalin. Water Treat., 2016, 1.
[85] 程康(Cheng K), 陈良(Chen L). 环境科技(Environment Science and Technology), 2015, 28(5):21.
[86] Li X H, Dou X M, Li J Q. J. Environ. Sci., 2012, 24(7):1197.
[87] Lu H T, Zhu Z L, Zhang H, Zhu J Y, Qiu Y L. Chem. Eng. J., 2015, 276:365.
PDF
(5273KB)
