Judicious utilization of host-guest supramolecular interactions and flexibilities of both the host and guest enables metal-organic frameworks to show abnormal adsorption selectivities for the less polar, more saturated hydrocarbons, which is useful for efficient purification of high-value alkenes such as ethylene and butadiene.
Judicious utilization of host-guest supramolecular interactions and flexibilities of both the host and guest enables metal-organic frameworks to show abnormal adsorption selectivities for the less polar, more saturated hydrocarbons, which is useful for efficient purification of high-value alkenes such as ethylene and butadiene.
[1] Sholl D S, Lively R P. Nature, 2016, 532:435. DOI:10.1038/532435a.
[2] Bao Z, Chang G, Xing H, Krishna R, Ren Q, Chen B. Energy Environ. Sci., 2016, 9:3612. DOI:10.1039/C6EE01886F.
[3] Bloch E D, Queen W L, Krishna R, Zadrozny J M, Brown C M, Long J R. Science, 2012, 335:1606. DOI:10.1126/science.1217544.
[4] Cadiau A, Adil K, Bhatt P M, Belmabkhout Y, Eddaoudi M. Science, 2016, 353:137. DOI:10.1126/science.aaf6323.
[5] Cui X L, Chen K J, Xing H B, Yang Q W, Krishna R, Bao Z B, Wu H, Zhou W, Dong X L, Han Y, Li B, Ren Q L, Zaworotko M J, Chen B L. Science, 2016, 353:141. DOI:10.1126/science.aaf2458.
[6] Li L, Lin R B, Krishna R, Wang X, Li B, Wu H, Li J, Zhou W, Chen B. J. Am. Chem. Soc., 2017, 139:7733. DOI:10.1021/jacs.7b04268.
[7] Herm Z R, Wiers B M, Mason J A, van Baten J M, Hudson M R, Zajdel P, Brown C M, Masciocchi N, Krishna R, Long J R. Science, 2013, 340:960. DOI:10.1126/science.1234071.
[8] Liao P Q, Zhu A X, Zhang W X, Zhang J P, Chen X M. Nat. Commun., 2015, 6:6350. DOI:10.1038/ncomms7350.
[9] Liao P Q, Zhang W X, Zhang J P, Chen X M. Nat. Commun., 2015, 6:8697. DOI:10.1038/ncomms9697.
[10] Liao P Q, Huang N Y, Zhang W X, Zhang J P, Chen X M. Science, 2017, 356:1193. DOI:10.1126/science.aam7232.
PDF
(1569KB)
