热电材料是一种可以实现热能与电能之间直接相互转换的功能材料，在温差发电和热电制冷方面具有广阔的应用空间。石墨烯是一种单原子层厚度的二维碳材料，具有特殊的晶体结构和优异的物理化学性质。大量研究表明石墨烯优异的电学性能、超大的比表面积以及多样的边界结构有利于材料电、热性能的协同调控，使其在热电领域有较大的应用潜力。本文结合热电材料的性能特点，从石墨烯的结构与性能入手，综述了石墨烯自身作为热电材料时结构与性能的优化关系，并总结归纳了石墨烯与Bi2Te3、CoSb3等传统无机热电材料以及与导电高分子热电材料构成纳米复合块体和薄膜时，对材料结构与热电性能的影响，并结合现存的问题对石墨烯在热电领域中的应用进行了展望。
Thermoelectric materials are one kind of functional materials, which can realize the direct conversion between electrical energy and thermal energy, and have wide applications in the fields of thermoelectric power generation and refrigeration. Graphene is a two-dimensional carbon material of a single atomic layer with special crystal structure and excellent physical and chemical properties. Many research demonstrate that the excellent electrical performance, large surface and various boundary structures of graphene can optimize the electrical and thermal performance of materials, making graphene of great application potentials in the field of thermoelectrics. In this paper, based on the characteristics of thermoelectric materials and graphene, the relationship of structure and performance of graphene when graphene itself is researched as thermoelectric material is reviewed. The effect of graphene on the microstructure and performances of conventional inorganic thermoelectric materials and conducting polymer thermoelectric materials when graphene is used to form nanocomposites with these thermoelectric materials are also summarized. In addition, the exiting problems and further outlook of the applications of graphene in the field of thermoelectric are discussed.
Contents
1 Introduction
2 Structure and property of graphene
3 Thermoelectric performance of graphene itself
4 Application of graphene in other thermoelectrics as composite
4.1 Nanocomposites of graphene and conventional inorganic thermoelectrics
4.2 Nanocomposites of graphene and conductive polymer thermoelectrics
5 Conclusion
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