铜基电催化剂还原CO2

刘孟岩, 王元双, 邓雯, 温珍海

doi:10.7536/PC170810

化学进展 ›› 2018, Vol. 30 ›› Issue (4) :398-409 DOI: 10.7536/PC170810

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铜基电催化剂还原CO₂

刘孟岩, 王元双, 邓雯, 温珍海

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Electrocatalytic Reduction of CO₂ on Copper-Based Catalysts

Mengyan Liu, Yuanshuang Wang, Wen Deng, Zhenhai Wen

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摘要

温室气体CO₂的大量排放给全球气候造成潜在威胁，电化学还原CO₂为有用的化工产品作为一种人为的碳循环的方式，拓展了新的利用CO₂的可能性，并且是一种很有前景的显著改善环境、促进可持续发展的方法。然而，在转化CO₂为有价值的产品过程中，最大的挑战是抑制析氢副反应的同时达不到高效率、高选择性。铜因其在电催化还原CO₂过程中优异的催化性能而得到广泛关注。本文重点介绍了近年来电催化还原CO₂的发展以及电化学转化CO₂的优缺点，介绍了CO₂RR的热力学与动力学研究并概述了Cu电极、Cu MOFs材料电极以及通过氧化、合金化、纳米化和表面修饰等方法修饰的铜电极的进展，但是电催化还原CO₂的反应机理尚不太确定。最后，讨论了未来铜基电极催化剂高效率地选择性转化CO₂会面临的挑战和可能研究的方向。

Abstract

The increasing greenhouse gas CO₂ emission poses a potential threat to global climate. Electrochemical reduction of CO₂ (CO₂RR) to useful chemical products, an artificial way of carbon recycling, opens up new possibilities of utilization of CO₂ and represents one promising solution that significantly improve the environment and promotes sustainable development. However, it remains a challenge to convert CO₂ to valued products with high efficiency and selectivity while suppressing the H₂ evolution(HER) side reaction. Copper attracts considerable attention currently because it displays interesting electrocatalytic performances for the reduction of CO₂. Progress related to the electrocatalytic reduction of CO₂ in the past few years, and their advantages and disadvantages are reviewed, and thermodynamics and kinetics research of CO₂RR is described,with a focus on the progress in CO₂RR on copper-based electrodes, which includes Cu electrode, Cu metal-organic frameworks electrode and Cu-based electrodes modified by oxidation, alloying, nanocrystalization and surface modification, even if the CO₂ electrocatalytic reduction reaction mechanism remains uncertain. Finally, challenges and future research opportunities for tuning the selective conversion of CO₂ on copper-based catalysts with high efficiency are also discussed.
Contents
1 Introduction
2 Research on the mechanism of electrocatalytic reduction of CO₂
2.1 Thermodynamics and kinetics of electrochemical reduction of CO₂
2.2 Research on the reaction mechanism of electrochemical reduction of CO₂
3 Electrochemical reduction of CO₂ on copper-based electrocatalysts
3.1 Copper electrode
3.2 Copper metal-organic framework electrode
3.3 Modified copper electrode
4 Conclusion

Graphical abstract

关键词

二氧化碳 / 电化学还原 / 铜基催化剂 / 碳氢化合物

Key words

carbon dioxide / electrochemical reduction / copper-based catalysts / hydrocarbon

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刘孟岩, 王元双, 邓雯, 温珍海. 铜基电催化剂还原CO₂[J]. 化学进展, 2018, 30(4): 398-409 DOI:10.7536/PC170810

Mengyan Liu, Yuanshuang Wang, Wen Deng, Zhenhai Wen. Electrocatalytic Reduction of CO₂ on Copper-Based Catalysts[J]. Progress in Chemistry, 2018, 30(4): 398-409 DOI:10.7536/PC170810

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