煤气化可弃型催化剂

吕记巍; 敖先权*; 陈前林; 谢燕; 曹阳; 张纪芳

doi:10.7536/PC171233

化学进展 ›› 2018, Vol. 30 ›› Issue (9) :1455-1462 DOI: 10.7536/PC171233

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煤气化可弃型催化剂

吕记巍, 敖先权*, 陈前林, 谢燕, 曹阳, 张纪芳

作者信息 +

Disposable Catalysts for Coal Gasification

Jiwei Lv, Xianquan Ao*, Qianlin Chen, Yan Xie, Yang Cao, Jifang Zhang

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文章历史 +

摘要

煤的高效催化气化技术是提高煤气化效率的重要途径。目前，除CaCO₃以外，其他碱金属、碱土金属与过渡金属类催化剂都由于成本较高、回收困难等问题并未广泛应用。可弃型催化剂具有廉价、不必回收、环保并兼有调节灰熔特性、固硫等优点，近年来在煤气化领域的研究和应用受到广泛关注。本文综述了国内外几类可弃型催化剂在煤气化领域的研究进展，包括钙基、工业废液、废渣和生物质灰等催化剂的催化特性及其机理，讨论了在实际应用中存在的问题，展望了未来煤气化可弃型催化剂的发展前景。

Abstract

Catalytic coal gasification technology is essential to improve the efficiency of coal gasification. At present, alkali metals, alkaline earth metals and transition metal catalysts have poor application induced by their high cost and difficulty in recovery except for CaCO₃. Disposable catalysts have got a multitude of attention on research and application of coal gasification in recent years, which have the advantages of being cheap, disposable, environmentally friendly, and capable of adjusting the ash melt characteristic and sulfation reaction. In this paper, the progress of several kinds of disposable catalysts in the field of coal gasification is reviewed, including the catalytic properties and mechanism of catalysts such as calcium based catalysts, waste water catalysts, waste solid catalysts and biomass ash catalysts, the problems in practical application are discussed, and the challenges and perspectives of the coal gasification catalysts are also prospected.
Contents
1 Introduction
2 Types of disposable catalysts and their catalytic mechanism
2.1 Calcium based catalysts
2.2 Industrial waste water catalysts
2.3 Industrial waste solid catalysts
2.4 Biomass catalysts
3 Conclusion and outlook

Graphical abstract

关键词

煤气化 / 催化 / 可弃型催化剂 / 催化机理

Key words

coal gasification / catalysis / disposable catalyst / catalytic mechanism

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吕记巍, 敖先权*, 陈前林, 谢燕, 曹阳, 张纪芳. 煤气化可弃型催化剂[J]. 化学进展, 2018, 30(9): 1455-1462 DOI:10.7536/PC171233

Jiwei Lv, Xianquan Ao*, Qianlin Chen, Yan Xie, Yang Cao, Jifang Zhang. Disposable Catalysts for Coal Gasification[J]. Progress in Chemistry, 2018, 30(9): 1455-1462 DOI:10.7536/PC171233

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