大气颗粒中小分子有机胺的检测方法和分布特征

王梅; 陈江耀; 李桂英; 安太成

doi:10.7536/PC20260306

化学进展 ›› :0- DOI: 10.7536/PC20260306

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大气颗粒中小分子有机胺的检测方法和分布特征

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Detection Methods and Distribution Characteristics of Small Molecule Amines in Atmospheric Particles

Mei Wang, Jiangyao Chen, Guiying Li, Taicheng An^*()

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摘要

有机胺类物质来源广泛以及其性质复杂，对空气质量和人体健康产生不利影响。并且对于大气中新粒子的形成和随后的增长具有重要意义。环境中的有机胺类对新粒子形成、气溶胶酸度以及气候变化均有影响。中国不同地区细颗粒物(PM_2.5)中有机胺类物质的组成、来源和形成过程的也均有差异。因此，近年来所涉及的过程受到越来越多的关注。精准检测大气颗粒中的有机胺，对于深入剖析其在大气新粒子的形成、气溶胶转化过程及其潜在健康效应中的作用意义重大。因此，本文对近年来国内外相关研究进行了归纳总结，系统梳理了大气颗粒中小分子有机胺类的检测方法与环境分布特征。研究表明，大气颗粒中小分子有机胺类的检测方法主要包括色谱法、质谱法以及色谱-质谱联用技术。色谱法侧重分离，质谱法侧重定性定量，色谱-质谱联用兼具高分离度与高灵敏结构解析能力。利用这些检测方法探究不同城市中颗粒物中小分子有机胺类的分布特征，我们发现它们存在不同区域和不同季节的差异。重点从检测方法的适用性与互补性角度出发，对不同分析技术在实际大气环境研究中的应用特点进行了比较，并结合中国典型大气污染情景分析，对该领域未来的发展方向进行了展望。

Abstract

Organic amine substances have a wide range of sources and complex properties, which have adverse effects on air quality and human health. Moreover, they are of great significance for the formation and subsequent growth of new particles in the atmosphere. Organic amines in the environment have an impact on the formation of new particles, aerosol acidity, and climate change. The composition, sources and formation processes of organic amine substances in fine particulate matter (PM_2.5) vary in different regions of China. Therefore, the processes involved in recent years have received increasing attention. Precise detection of organic amines in atmospheric particles is of great significance for in-depth analysis of their roles in the formation of new atmospheric particles, the transformation of aerosols, and potential health effects. This article systematically reviews the detection methods and distribution characteristics of small-molecule organic amines in atmospheric particles. The detection methods for small-molecule organic amines in atmospheric particles mainly include chromatography, mass spectrometry, and chromatography-mass spectrometry coupling technology. Chromatography focuses on separation, mass spectrometry focuses on qualitative and quantitative analysis, and chromatography-mass spectrometry coupling combines high separation efficiency with high sensitivity for structural analysis. By using these detection methods to explore the distribution characteristics of small-molecule organic amines in particulate matter in different cities, we found that there are differences in different regions and different seasons. From the perspective of the applicability and complementarity of the detection methods, the application characteristics of different analytical techniques in actual atmospheric environment research were also compared, and the future development direction of this field was perceptive in combination with typical atmospheric pollution scenarios in China.

关键词

颗粒相有机胺 / 环境分布特征 / 色谱分析 / 质谱监测技术 / 大气气溶胶

Key words

organic amines in particulate phase / environmental distribution characteristics / chromatographic analysis / mass spectrometry determination technology / atmospheric aerosols

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王梅, 陈江耀, 李桂英, 安太成. 大气颗粒中小分子有机胺的检测方法和分布特征[J]. 化学进展, , (): 0 DOI:10.7536/PC20260306

Mei Wang, Jiangyao Chen, Guiying Li, Taicheng An. Detection Methods and Distribution Characteristics of Small Molecule Amines in Atmospheric Particles[J]. Progress in Chemistry 0 DOI:10.7536/PC20260306

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Received	Published	Revised
2026-03-13	2026-09-03	2026-04-25
Online Date
2026-09-03

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