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MOF-COF框架杂化材料
MOF-COF Hybrid Frameworks Materials
金属有机框架(MOF)和共价有机框架(COF)材料是两种多孔的晶态材料,具备较大的比表面积、高的孔隙率,结构合成修饰方法丰富,因此在析氢、析氧、CO2还原、有机物降解、气体分离等多个方面都有应用前景。但MOF、COF自身仍有许多缺点,如MOF在水溶液中不稳定,结构易塌陷,COF无金属节点,功能较简单,催化性能有待进一步提高等。近年来,MOF-COF核壳杂化材料结合两种材料的优势解决各自的一些缺陷,有广泛的应用潜力,作为新的发展方向受到了关注。本文从MOF-COF杂化材料的类型、合成方法、应用等三个方面综述了近些年来MOF-COF材料的发展状况,并做出了展望。
Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are two porous crystalline materials, which have a large specific surface area, and high porosity and can be synthesized and modified via various methods. Therefore, they have found potential applications in hydrogen evolution, oxygen evolution, CO2 reduction, organic pollution degradation, gas separation and so on. However, MOF and COF still have many defects themselves. For example, most MOFs are unstable in the aqueous solution due to the collapse of the structures; and COFs with no metals involved are poor in catalytic performance. Furthermore, COFs normally lack certain functions. As a new area, MOF-COF hybrid materials have been explored in recent years. They can combine the characteristics of the two materials to solve some of their own defects, and have a wide range of application prospects. Herein, this article summarizes the development of MOF-COF materials in recent years from three aspects: the types, synthetic methods and applications of MOF-COF hybrid materials. A prospect is also proposed.
1 Introduction
1.1 MOF materials
1.2 COF materials
1.3 MOF-COF hybrid materials
2 Synthesis
2.1 MOF-on-COF
2.2 COF-on-MOF
3 Applications
3.1 Catalysis
3.2 Absorption and separation
3.3 Sensing
3.4 Others
4 Conclusion and outlook
核壳杂化 / MOF@COF / COF@MOF / 多孔材料
core-shell hybridization / MOF@COF / COF@MOF / porous materials
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国家自然科学基金项目(22078241)
中央高校基本科研业务费专项资金资助
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