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New Development of Key Materials for High-Performance Lithium-Air Batteries

Progress in Chemistry ›› 2013, Vol. 25 ›› Issue (0203) : 260 -269.

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Progress in Chemistry ›› 2013, Vol. 25 ›› Issue (0203) : 260-269 DOI: 10.7536/PC120616
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New Development of Key Materials for High-Performance Lithium-Air Batteries
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Abstract

Electrochemical power sources based on < anode metal | electrolyte | cathode oxygen > configuration have the highest energy density because the cathode active material(oxygen) is not stored in the battery, but can be accessed from the environment. Rechargeable lithium-air battery has been receiving more attention due to its high theoretical energy density of 5 210 Wh  ·g-1, and it is considered as the next generation portable energy supply device for electronic vehicle(EV) and hybrid vehicle(HEV). This system has been understood by people in recent years. Although there are many unknown mechanisms in the electrochemical process of charge/discharge of the lithium-air battery, some achievements have been made on the development of oxygen reduction catalyst, air electrode materials and electrolyte materials. This paper reviews the achievements on lithium-air battery in the past few years from the respects of lithium-air battery system,cathode materials,electrolytes and lithium anode. The weaknesses are revealed and the future is prospected. Contents
1 Introduction
2 The main issues of lithium-air battery
3 Protection of lithium anode
4 Research on the electrolytes
4.1 Organic system electrolytes
4.2 Ionic liquid
4.3 Solid electrolyte
4.4 Aqueous electrolyte
5 Research on the air cathode
5.1 Porosity of air cathode
5.2 Efficiency of catalyst
6 Conclusions and perspective

Keywords

lithium-air battery / air electrode / electrolyte / lithium anode

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Huang Zheng, Chi Bo, Pu Jian, Li Jian*. New Development of Key Materials for High-Performance Lithium-Air Batteries. Progress in Chemistry, 2013, 25(0203): 260-269 DOI:10.7536/PC120616

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