Synthesis and Applications in Catalysis of Porphyrinic Metal-Organic Frameworks
Progress in Chemistry ›› 2014, Vol. 26 ›› Issue (0203) : 277 -292.
Heterogeneous catalysis is one of the promising applications for metal-organic frameworks (MOFs) materials because of their high porosity, large surface areas and their flexible tailoring. An attractive approach to design MOFs-based catalysts is to heterogenize them by employing known homogeneous molecular catalysts as struts. In view of the enormous utility as active sites in metallo-enzymes, metalloporphyrin is obvious candidates for incorporation into MOFs as catalytically functional struts. Many efficient strategies have been established for the rational design and synthesis of catalytically functional porphyrinic MOFs. This review is aimed to summarize recent progress on porphyrinic MOFs, including new synthesis strategies and applications in catalysis. The development trends of porphyrinic MOFs are also prospected.
Contents
1 Introduction
2 Synthesis strategies for porphyrinic MOFs
2.1 Utility of extendable porphyrinic ligands in generating secondary building units (SBUs)
2.2 Using specially designed spacers to stabilize secondary building units (SBUs)
2.3 Combination of mixed-ligands
2.4 Template-directed synthesis
3 Heterogeneous catalytic performances of porphyrinic MOFs
3.1 MOFs-based catalysts constructed by porphyrinic ligands
3.2 Catalytic reactions of MOFs-encapsulated porphyrinic catalysts
4 Conclusions and outlook
porphyrin
/
| 〈 |
|
〉 |