During last several decades, organic/inorganic hybrid materials have been used widely in many fields due to their excellent structure and performance. Thiol-ene/yne click chemistry, a new type of click chemistry, is of great interest because of its mild reaction conditions, fast reaction rate, high yield, easy post-treatment and high selectivity for the obtained products. Therefore, synthesis of high-performance organic/inorganic hybrid materials via thiol-ene/yne click chemistry is one of the hot topics of novel material research. In this review, the recent research progress of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry is discussed. Synthesis of silicon-, carbon-, metal- and metal oxide-based organic/inorganic hybrid materials via thiol-ene/yne click chemistry is highlighted. In addition, the applications of these hybrid materials in the fields of biomedical materials, environment protection and photoelectric materials are summarized. Finally, the development trend and future prospects of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry are presented.

Contents
1 Introduction
2 Organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry
2.1 Synthesis of silicon-based organic/inorganic hybrid materials
2.2 Synthesis of carbon-based organic/inorganic hybrid materials
2.3 Synthesis of metal- and metal oxide-based organic/inorganic hybrid materials
3 Application of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry
3.1 Biomedical materials
3.2 Environmental protection
3.3 Photoelectric materials
3.4 Other application
4 Conclusions and outlook