The study of nitrogen-coordinating transition metal complexes has been a significant development in the recent decades. Designing different excellent nitrogen ligands coordinated with various transition metal complexes, which its of great value in hydrosilylation reaction. In this paper, the latest progress of the application in nitrogen-coordinating transition metal(Rh, Fe, Re, Co, Zn and so on)complexes to ketone hydrosilylation or alkene hydrosilylation is reviewed. The design of optimized bisoxazolines or dihydropyrrolo nitrogen-containing ligands will greatly facilitate the successful development of nitrogen-containing iron, rhenium, cobalt complexes in the hydrosilylation of ketone or imine.

Contents
1 Introduction
2 The application on nitrogen-coordinating transition metal complexes on hydrosilylation
2.1 The application on nitrogen-coordinating rhodium complexes on hydrosilylation
2.2 The application on nitrogen-coordinating iron complexes on hydrosilylation
2.3 The application on nitrogen-coordinating rhenium complexes on hydrosilylation
2.4 The application on nitrogen-coordinating cobalt complexes on hydrosilylation
2.5 The application on nitrogen-coordinating zinc complexes on hydrosilylation
2.6 The application on nitrogen-coordinating titanium complexes on hydrosilylation
3 The study of mechanism
4 Conclusion