中文   |   English   |   Email Alert

Lithium-Ion Battery Electrolyte Containing Fluorinated Solvent and Additive

Progress in Chemistry ›› 2016, Vol. 28 ›› Issue (9) : 1299 -1312.

PDF (5788KB)
Progress in Chemistry ›› 2016, Vol. 28 ›› Issue (9) : 1299-1312 DOI: 10.7536/PC151212
Scan to read & Share
Lithium-Ion Battery Electrolyte Containing Fluorinated Solvent and Additive
Author information +
History +
PDF (5788KB)

Abstract

With the development of large mobile equipments (such as electric vehicles), energy storage power stations and the other portable charging devices, lithium-ion battery is gradually occupying the dominant position of the chemical power market. Electrolyte is one of the most important components of lithium-ion battery, having a significant impact on many properties of lithium-ion battery, such as the output voltage, energy density, power density, longevity, temperature range, safety performance and so on. In general, owing to the very high electronegativity and low polarizability of fluorine, fluorinated organic solvent shows very different physical properties compared to the common organic solvent. Specifically, fluorinated solvent has a low melting point, high flash point, high oxidation decomposition voltage, and good wettability with the electrode material. Therefore, fluorinated solvent has a potential application in the research and development for high voltage electrolyte, high security electrolyte, wide temperature window liquid electrolyte, and the other special functional electrolyte. Here, the recent research and applications on fluorinated solvents and additives in lithium-ion battery electrolyte are reviewed. The mechanisms for the enhancement performance of lithium-ion battery electrolyte with the use of fluorinated solvents and additives are also analyzed and discussed in detail. Simultaneously, the fabrication methods of fluorinated solvents such as fluorinated ethylene carbonate (FEC) are summarized. Finally, the research prospects and problems for fluorinated solvents and additives in lithium-ion battery electrolyte are also discussed in detail.

Contents
1 Introduction
2 High-voltage electrolyte
2.1 The solvent of high-voltage electrolyte
2.2 The additive of high-voltage electrolyte
3 High security electrolyte
3.1 The nonflammable electrolyte containing flrorinated solvent
3.2 Fluorinated flame retardant additives
4 High and low temperature electrolyte
4.1 High temperature electrolyte
4.2 Low temperature electrolyte
5 The other functional electrolytes
5.1 Fluorinated solvent and additive with special function
5.2 The application of fluorinated solvent and additive in new type battery

Keywords

lithium-ion battery / electrolyte / fluorine chemical / additive

Cite this article

Download citation ▾
Ma Guoqiang, Wang Li, Zhang Janjun, Chen Huichuang, He Xiangming, Ding Yuansheng. Lithium-Ion Battery Electrolyte Containing Fluorinated Solvent and Additive. Progress in Chemistry, 2016, 28(9): 1299-1312 DOI:10.7536/PC151212

登录浏览全文

4963

注册一个新账户 忘记密码

References

PDF (5788KB)

3662

Accesses

0

Citation

Detail

Sections
Recommended

/

〈 〉