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Abstract
Photocatalytic technology based on semiconductor materials is expected to use clean solar energy to control the environmental pollution and ease the energy shortages.In recent years, some silver-containing semiconductor materials with narrow band gap exhibit excellent oxidation and reduction ability under visible light irradiation, hence, silver-containing photocatalysts have become one of the focuses in the field of photocatalytic materials. Single silver-containing photocatalytic materials have high cost and poor stability, which limit their practical applications. As a result, the composite photocatalytic materials have been widely studied. Recently, simulating the photosynthesis process of green plants, all-solid-state Z-scheme photocatalytic systems are established, which can enhance the stability and reduce the cost of silver-containing photocatalytic materials as well as improve their photocatalytic performances. In this paper, we firstly describes the derivation and reaction mechanism about the all-solid-state Z-scheme photocatalytic systems, and then reviews the construction, application and reaction mechanism of silver-containing semiconductor materials-based all-solid-state Z-scheme photocatalytic systems so far.At last, we point out some existing problems about these silver-containing semiconductor materials-based Z-scheme photocatalytic systems, and their research prospects are also proposed.
Contents
1 Introduction
2 The derivation and reaction mechanism of all-solid-state Z-scheme photocatalytic systems
3 The research findings of silver-containing semiconductor materials-based Z-scheme
photocatalytic systems
3.1 AgX-based Z-scheme photocatalytic systems
3.2 Ag3PO4-based Z-scheme photocatalytic systems
3.3 Ag2CO3-based Z-scheme photocatalytic systems
3.4 Ag2MO4-based Z-scheme photocatalytic system
4 Conclusion
Graphical abstract
Keywords
silver-containing materials
/
visible light
/
Z-scheme system
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photocatalytic application
/
reaction mechanism
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Ming Ge, Zhenlu Li.
All-Solid-State Z-Scheme Photocatalytic Systems Based on Silver-Containing Semiconductor Materials.
Progress in Chemistry, 2017, 29(8): 846-858 DOI:10.7536/PC170543