Tianium, nickel and iron complexes as catalysts have been widely applied in numerous catalytic organic reactions, in which these complexes show excellent catalytic performance and have been recognized as very important research field. We summarize the recent progress in the synthesis of titanium, nickel and iron complexes and their application in the catalytic hydrosilylation of alkenes, alkynes, carbonyl compounds and other unsaturated double bond, triple bond compounds. Furthermore, the deficiencies of the catalysts have been discussed. At last, the future development and prospects of these complexes as catalysts are also proposed.
Contents
1 Introduction
2 Application of the tianium complexes in the hydrosilylation
3 Application of the nickel complexes in the hydrosilylation
4 Application of the iron complexes in the hydrosilylation
5 Conclusion