Environmental endocrine disruptors(EEDs) have very serious harms to human health and ecological environment, thus it is of great significance to develop efficient technologies to detect and remove EEDs in real environmental samples. Due to their traits of high adsorption selectivity, large adsorption ability and good regeneration ability, molecularly imprinted polymers(MIPs) have become more and more important in the applications of detection and removal of EEDs. In this paper, the features of EEDs and their application in our daily life, in industries and other aspects are introduced. And also the characteristics, preparation methods and performance characteristics of MIPs are described. In addition, the applications of MIPs based on solid phase extraction(SPE) method and sensor technology in the sensitive and specific detection of the low background concentration EEDs, and also the applications of MIPs based on adsorption technology and other hyphenated techniques in the selective, fast and efficient removal of EEDs, are reviewed. Furthermore, the study work of our laboratory in this respect are presented in this review. Last but not least, the problems in the synthesis and use of MIPs are also analyzed in detail, and the applications of MIPs in the future are prospected.