Synthesis of Sludge Carbon-Based Catalytic Materials and Their Application in Water Environment
Lin Gu , Kai Zhang , Haixiang Yu , Guangxia Dong , Xingbo Qiao , Haifeng Wen
Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (9) : 1412 -1426.
With dual attributes of pollutant and resources, sewage sludge(SS) is the byproduct from wastewater treatment plant, which belongs to typical urban solid waste. The use of SS as raw materials for the synthesis of carbon-based catalysts and their application in water environment catalysis is an implement of sludge reduction and resource reutilization. As SS is a mixture of organic matter from biomass and various inorganic oxides and metal ions, the carbon-based catalyst or carrier prepared from SS has the properties of easy availability of raw materials, strong dispersibility of active components on the carrier, easy adjustment of surface chemical functional groups, and high specific surface area. It is widely used in the field of multiphase Fenton reaction, electrochemical catalytic oxidation, complex photocatalytic reaction, catalytic wet oxidation and catalytic ozonation. This paper will describe the preparation and modification methods of sludge carbon-based catalyst materials. In addition, the mechanism, which carbon-based catalysts participate in pollutant adsorption, electron transfer, and organic degradation in water, is explained by the structure-activity relationship between physico-chemical properties of materials and catalytic action, combined with its application characteristics in the field of water environment catalysis. At the same time, a new prospect is put forward to improve the stability, reusability and catalytic activity of sludge-based materials.
1 Introduction
2 Physical and chemical properties of sludge carbon-based precursors
2.1 Chemical composition
2.2 Physical structure
2.3 Surface chemical properties
3 Sludge carbon-based catalyst material preparation method
3.1 Direct pyrolysis
3.2 Load method
3.3 Blending method
3.4 Hydrothermal carbonization
4 Surface modification of sludge carbon-based catalyst materials
5 Application of sludge carbon-based catalyst in the field of water environment catalysis
5.1 Catalytic H2O2 heterogeneous Fenton reaction
5.2 Catalytic degradation based on persulfate(PS) and peroxymonosulfate(PMS)
5.3 Composite photocatalytic reaction
5.4 Heterogeneous catalytic ozonation
5.5 Heterogeneous catalytic wet oxidation
5.6 Electrochemical catalytic oxidation
6 Stability of sludge carbon-based catalyst
7 Conclusion and outlook
sludge / carbonized materials / catalyst / organic pollutants
the National Natural Science Foundation of China(51408358)
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