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Enhancing the Stability of Lithium-Rich Manganese-Based Layered Cathode Materials for Li-Ion Batteries Application

Zhiyuan Lu , Yanni Liu , Shijun Liao

Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (10) : 1504 -1514.

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Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (10) : 1504-1514 DOI: 10.7536/PC200220
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Enhancing the Stability of Lithium-Rich Manganese-Based Layered Cathode Materials for Li-Ion Batteries Application
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Abstract

Lithium-rich manganese-based layered cathode materials (xLi2MnO3·(1-x)LiMO2, M=Ni, Co, Mn, etc.), owing to their high specific capacity (≥ 250 mAh·g-1), low cost and environmental friendliness, are considered as one of the best candidate cathode materials for the new generation of lithium-ion batteries. However, these materials suffer from severe capacity/voltage fading during the cycle process and low rate capability which seriously hinder commercial development. In this paper, we analyze the structural characteristics and the reasons which lead to the deterioration of the electrochemical performance of the lithium-rich manganese-based layered cathode materials, systematically review the latest progress and achievements on improving the stability of the cathode materials, and the efforts to improve the electrochemical properties of the cathode materials through bulk doping and surface modification. In this process, the effects of bulk doping at different sites and different coating materials on the structure and electrochemical behavior of lithium-rich manganese-based layered cathode materials are further analyzed. Finally, considering the advantages and disadvantages of the two modification methods of bulk doping and surface coating, a joint modification mechanism combining bulk doping and surface coating has been suggested to improve the stability of lithium-rich cathode materials in the long cycle process, and the introduction and prospect of this mechanism are also given.

Contents

1 Introduction

2 Structural characteristic and electrochemical behaviors of lithium-rich manganese-based materials

2.1 Lithium-rich manganese-based materials and its structural characteristic

2.2 Charge-discharge reaction mechanism

2.3 Structural evolution and decay mechanism

3 Bulk doping improves the cycle stability of lith- ium-rich manganese-based materials

3.1 Li site doping

3.2 TM site doping

3.3 O site doping

4 Surface modification improves the cycle stability of lithium-rich manganese-based materials.

4.1 Surface coating

4.2 Surface treatment

5 A joint mechanism

6 Conclusion and outlook

Graphical abstract

Keywords

lithium-rich manganese-based layered cathode materials / cycle stability / bulk doping / surface modification

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Zhiyuan Lu, Yanni Liu, Shijun Liao. Enhancing the Stability of Lithium-Rich Manganese-Based Layered Cathode Materials for Li-Ion Batteries Application. Progress in Chemistry, 2020, 32(10): 1504-1514 DOI:10.7536/PC200220

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References

Funding

National Key Research and Development Program of China(2017YFB0102900)

National Key Research and Development Program of China(2016YFB0101201)

National Natural Science Foundation of China(21476088)

National Natural Science Foundation of China(21776104)

Guangdong Provincial Department of Science and Technology(2015B010106012)

Guangzhou Science Technology and Innovation Committee(201504281614372)

Guangzhou Science Technology and Innovation Committee(2016GJ006)

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