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All-Inorganic Perovskite Solar Cells: Status and Future

Xiaohui Ma , Liqun Yang , Shijian Zheng , Qilin Dai , Cong Chen , Hongwei Song

Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (10) : 1608 -1632.

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Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (10) : 1608-1632 DOI: 10.7536/PC200313
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All-Inorganic Perovskite Solar Cells: Status and Future
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Abstract

In recent years, organic-inorganic hybrid perovskite materials based on the ABX3 structure have attracted worldwide attention due to their excellent optoelectronic properties and cheap manufacturing costs. However, the organic components in the system are elementary to be resolved under the influence of light, heat, humidity, and other external conditions, which greatly limits the industrialization of the PSCs(Perovskite solar cells). All-inorganic perovskite materials prepared by using pure inorganic cations to replace the A-site organic cations in ABX3 structure have been developed rapidly due to their excellent thermal stability and environmental stability. At present, the efficiency of all-inorganic perovskite solar cells(I-PSCs) has exceeded 19% with broad application prospects. The research progress of inorganic perovskite materials and the different types of inorganic perovskite materials are reviewed. Meanwhile, the ways to improve the stability of devices from the aspects of films forming process, doping engineering, post-processing engineering, etc. are summarized Finally, we introduced the large-area preparation and flexible application of I-PSCs, reveals the challenges faced by I-PSCs and summarizes the prospect of the field.

Contents

1 Introduction

2 Basic of I-PSCs

2.1 Crystal structure of inorganic perovskite

2.2 Working principle of I-PSCs

2.3 Device structure of I-PSCs

3 Preparation process of inorganic perovskite

3.1 Solution processing technology

3.2 Vacuum preparation technology

3.3 Other preparation methods

4 Inorganic Pb-based perovskite and devices

4.1 CsPbI3

4.2 CsPbBr3

4.3 CsPbI3-xBrx

4.4 Cs1+xPbI3+x

5 Inorganic Sn/Ge-based perovskite and devices

5.1 CsSnI3

5.2 CsSnBr3

5.3 CsSnI3-xBrx

5.4 CsGeI3

6 Perovskite derivatives and devices

7 Functional application of inorganic perovskite

8 Stability of inorganic perovskite

8.1 Phase stability

8.2 Light and thermal stability

9 Large-area preparation and flexible application

10 Conclusion and outlook

Graphical abstract

Keywords

all-inorganic / perovskite solar cells / doping / thermal stability / phase stability

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Xiaohui Ma, Liqun Yang, Shijian Zheng, Qilin Dai, Cong Chen, Hongwei Song. All-Inorganic Perovskite Solar Cells: Status and Future. Progress in Chemistry, 2020, 32(10): 1608-1632 DOI:10.7536/PC200313

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Funding

National Natural Science Foundation of China(51771201)

National Key Research and Development Plan of China(2016YFC0207101)

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