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Near-Infrared Light Responsive Liquid Crystal Elastomers

Meng Wang , Danyang Ma , Chengjie Wang

Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (10) : 1452 -1461.

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Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (10) : 1452-1461 DOI: 10.7536/PC200335
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Near-Infrared Light Responsive Liquid Crystal Elastomers
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Abstract

As one booming category of smart polymeric materials, stimuli-responsive liquid crystal elastomers (LCEs) are very promising owing to the large and reversible shape deformations response to external stimuli (heat, light, electric or magnetic field, etc.). Due to the changes of microscopic orders or molecular structures of uniaxial-aligned mesogens, the whole LCE materials could execute very large and reversible macroscopic actuation during the LC-to-isotropic phase transition process. Among them, near-infrared light (NIR-light) responsive LCEs have attracted scientific attention because NIR-light has a strong penetration and low toxicity to biological tissues. The NIR-induced deformation mechanisms of LCEs can be divided into two main categories. One is relying on the trans-cis variations of azobenzene chromophores triggered by NIR-light which can be converted into low-wavelength lights by doping inorganic or organic up-conversion materials. The other type of light-responsive LCEs takes advantage of the photo-thermal effect of thermal conductive fillers to transform light into heat which further induces the LC-to-isotropic phase transition and thus make the LCE materials shrink/expand. These characteristics endow NIR-light responsive LCE materials with potential applications as mechanical actuators, artificial organs, smart surfaces, microrobots, etc. This article reviewes the developments of NIR-light responsive LCEs, and also introduces the main deformation mechanisms and applications of NIR-light responsive LCEs in detail. Besides, the article further provides a view of prospective development in future for NIR-light responsive LCEs and actuators.

Contents

1 Introduction

2 Near-infrared light responsive liquid crystal elastomers based on up-conversion effect

3 Near-infrared light responsive liquid crystal elastomers based on photothermal effect

3. 1 Carbon photothermal materials

3. 2 Noble metal photothermal materials

3.3 Organic photothermal materials

3. 4 Semiconductor photothermal materials

4 Applications

4.1 Soft robots

4.2 Bionic devices

5 Conclusion and outlook

Graphical abstract

Keywords

liquid crystal elastomer / near-infrared light / photo-thermal effect / smart material / soft actuator

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Meng Wang, Danyang Ma, Chengjie Wang. Near-Infrared Light Responsive Liquid Crystal Elastomers. Progress in Chemistry, 2020, 32(10): 1452-1461 DOI:10.7536/PC200335

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Funding

National Natural Science Foundation of China(51903048)

Jiangsu Provincial Natural Science Foundation(BK20180406)

Fundamental Research Funds for the Central Universities(2242020K40034)

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