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Application of Metal-Organic Framework Materials in the Photocatalytic Carbon Dioxide Reduction

Xiao Feng , Yanwei Ren , Huanfeng Jiang

Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (11) : 1697 -1709.

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Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (11) : 1697-1709 DOI: 10.7536/PC200407
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Application of Metal-Organic Framework Materials in the Photocatalytic Carbon Dioxide Reduction
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Abstract

The effective use of CO2 has become a research hotspot worldwide, whose excessive emission led to increasingly serious global environmental problems. Compared with high energy-consuming CO2 capture and storage(CCS) technology, the photocatalytic conversion of CO2 into a valuable energy fuel is an effective way to solve energy and environmental problems. Among them, the development of a photocatalyst with efficient catalytic performance under visible light is the key to this process. Currently, there are still many shortcomings in photoreduction CO2 catalysts, such as weak visible light response ability, high recombination rate of photo-generated electron-hole pairs, low CO2 adsorption capacity, poor product selectivity, and hydrogen-evolution competition in an aqueous environment. Metal-organic frameworks(MOFs), with adjustable porous structures, fast electron migration rate, large CO2 adsorption capacity, etc., are a unique class of porous crystalline materials composed of metal ions/clusters and organic ligands, which have broad application potential in CO2 photocatalytic reduction. The existing methods improving the catalytic performance of MOFs-based catalysts is mainly to enhance the absorption of visible light by functional modification, formation of composites with other functional materials and so on. This review mainly analyzes and discusses the recent advances of MOFs-based photoreduction CO2 catalysts(single MOFs, MOFs-based composites and MOFs-derived materials), and predicts future development trends and prospects of MOFs-based materials in photocatalytic reduction of CO2.

Contents

1 Introduction

2 Single MOFs

2.1 Organic ligands as photosensitizer

2.2 Metalloligands as photosensitizer

3 MOFs-based composites

3.1 MOFs/semiconductor composites

3.2 MOFs/perovskite quantum dot composites

3.3 MOFs/noble metal nanoparticle composites

3.4 MOFs/enzyme composites

4 MOFs-derived materials

5 Conclusion and outlook

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Keywords

metal-organic framework / CO2 photoreduction / photocatalyst / MOFs-based composites / MOFs-derived materials

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Xiao Feng, Yanwei Ren, Huanfeng Jiang. Application of Metal-Organic Framework Materials in the Photocatalytic Carbon Dioxide Reduction. Progress in Chemistry, 2020, 32(11): 1697-1709 DOI:10.7536/PC200407

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(2016YFA0602900)

(2020B01088001)

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