Condensed State Chemistry in the Synthesis of Inorganic Nano- and Porous Materials
Jianlin Shi , Zile Hua
Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (8) : 1060 -1075.
Condensed state chemistry, as we know, means diverse chemical processes taking place in liquids and solids. Actually, condensed state chemistry is present throughout the synthesis and preparation of inorganic materials, especially the nano- and porous solid materials. In the material synthesis, obtaining target solids with desired chemical compositions and phase structures, is probably one of the most fundamental issues of condensed state chemistry. While in the synthesis of porous solid materials such as microporous zeolites or mesoporous oxides, the regulations of pore structures along with the chemical compositions and phase structures become important. Moreover, aiming at the applications in, e.g., catalysis and drug delivery, key factors such as the active sites and defects, and the geometric/physical features such as the dimensions, dispersity and morphologies, should be taken into considerations in addition to the issues mentioned above. In this feature article, by focusing on the inorganic oxides, we discuss several aspects of condensed state chemistry in the chemical syntheses of nanoparticles and superfine powders, pore structural regulations of mesoporous materials and composites, and the synthesis and catalytic properties of hierarchically porous structured zeolite, so as to acquire further in-depth understanding of condensed state chemistry in the materials synthesis and promote the development of nano-/porous inorganic solids under the guidance of condensed state chemistry.
===1 Introduction
===2 Condensed state chemistry for the preparation of nanoparticles and ultrafine powders
===2.1 Brief description about inorganic nanoparticles and ultrafine powders
===2.2 Characteristics of condensed state chemistry of inorganic nanoparticles and ultrafine powders
===2.3 General chemical methods for preparation of inorganic nanoparticles and ultrafine powders
===3 Condensed state chemistry for the preparation of nanomaterials and mesostructured nanocomposites
===3.1 Descriptions of condensed state chemistry routes for the preparation of nanocomposites
===3.2 Soft-templating preparation of mesoporous and mesostructured nanocomposites
===3.3 Inverse-replication preparation of crystallized mesoporous oxides and bicomponent mesoporous composites
===3.4 Template-free preparation of mesoporous metal oxides and composites
===3.5 Post-incorporation strategy for the preparation of mesoporous host-guest nanocomposites
===4 Condensed state chemistry in the preparation of hierarchically structured zeolites
===4.1 Etching preparation of hierarchically structured zeolites
===4.2 Templating preparation of hierarchically structured zeolites
===4.3 Template-free and self-templating preparation of hierarchically structured zeolites
===4.4 Perspectives on condensed state chemistry synthesis and applications of hierarchically structured zeolites
===5 Conclusion and remarks
condensed state chemistry / oxide nanoparticles / zeolites / mesoporous materials / nanostructured composites
the National Natural Science Foundation of China(21835007)
the National Natural Science Foundation of China(21776297)
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