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Condensed Matter Chemistry under High Pressure

Xiaoyang Liu

Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (8) : 1184 -1202.

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Progress in Chemistry ›› 2020, Vol. 32 ›› Issue (8) : 1184-1202 DOI: 10.7536/PC200435
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Condensed Matter Chemistry under High Pressure
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Abstract

This article introduces the effects of high-pressure conditions on the electronic structure and crystal structure of condensed matter, including the outer electronic structure, band structure and crystal defects, and also the increase in atomic coordination number, the element’s abnormal oxidation, structural phase transitions, and state transitions. At the same time, the chemical reactions of condensed matter under high pressure are introduced from ten aspects. Finally, the future development of condensed matter chemistry under high pressure is prospected.

Contents

1 Introduction

2 Effect of high pressure on the electronic and crystal structure of condensed matter

2.1 Effect of high pressure on the outer electronic structure of the elements

2.2 An increase in the atomic number caused by high pressure

2.3 Abnormal oxidation states of elements caused by high pressure

2.4 Structural phase transitions caused by high pressure

2.5 Effect of high pressure on band structure

2.6 Effect of high pressure on crystal defects

2.7 State changes caused by high pressure

3 Chemical reaction of condensed matter under high pressure

3.1 Metallization of hydrogen

3.2 High-pressure polymerization of small inorganic molecules

3.3 High-pressure polymerization of organic compounds

3.4 High-pressure synthesis of poly-nitrogen compounds

3.5 High-pressure synthesis of MOFs

3.6 High-pressure synthesis of inert element oxides

3.7 Reaction of alkali metal with inert gas under high pressure

3.8 Effect of high pressure on the morphology and structure of nanocrystals

3.9 Synthesis of Na-Cl compounds under high pressure

3.10 Promoting effect of high pressure on chemical reaction

4 Conclusions and outlook

Graphical abstract

Keywords

condensed matter chemistry / high-pressure / electronic structure / crystal structure / chemical reaction

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Xiaoyang Liu. Condensed Matter Chemistry under High Pressure. Progress in Chemistry, 2020, 32(8): 1184-1202 DOI:10.7536/PC200435

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References

Funding

the National Natural Science Foundation of China(21271082)

the National Natural Science Foundation of China(40673051)

the National Natural Science Foundation of China(20471022)

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