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Preparation and Application of Biodegradable Superabsorbent Polymer Microspheres

Chengjin Yu , Xiaxia Tang , Renjie Wang , Xianglin Yu

Progress in Chemistry ›› 2026, Vol. 38 ›› Issue (8) : 1481 -1489.

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Progress in Chemistry ›› 2026, Vol. 38 ›› Issue (8) : 1481-1489 DOI: 10.7536/PC20251204
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Preparation and Application of Biodegradable Superabsorbent Polymer Microspheres
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Abstract

Biodegradable superabsorbent polymers (SAPs) are known for their high swelling capacity and strong biodegradability. However, they suffer from insufficient mechanical properties. Spherical SAPs, on the other hand, exhibit better mechanical properties and thus hold more advantages in applications. This paper first briefly introduces the research progress of biodegradable superabsorbent polymer microspheres from three aspects: natural polymer-based, organic-inorganic composite-based and synthetic polymer-based. Subsequently, it focuses on the preparation methods, discussing commonly used inverse suspension polymerization, emulsion polymerization and dispersion polymerization. The scope of application, principles, advantages and disadvantages, and current research status of each method are summarized. Based on this, the paper introduces the recent combination of spherical technology and radiation polymerization for the preparation of biodegradable superabsorbent polymer microspheres. Finally, the application status and prospects of biodegradable superabsorbent polymer microspheres in the fields of agriculture and forestry, construction, and medical and health care are presented. The conclusion points out that the future research trend of biodegradable superabsorbent polymer microspheres lies in the in-depth study of organic-inorganic composite SAP and the exploration of new and eco-friendly synthesis pathways.

Contents

1 Introduction

2 Classification of biodegradable superabsorbent polymer microspheres

2.1 Natural polymer-based

2.2 Organic-inorganic composite-based

2.3 Synthetic polymer-based

3 Preparation of biodegradable superabsorbent polymer microspheres

3.1 Inverse suspension polymerization

3.2 Emulsion polymerization

3.3 Dispersion polymerization

4 Applications of biodegradable superabsorbent polymerization

4.1 Agriculture and forestry

4.2 Construction industry

4.3 Medical and health fields

5 Conclusion and outlook

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Keywords

superabsorbent polymer / microsphere / emulsions / polymers / preparation

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Chengjin Yu, Xiaxia Tang, Renjie Wang, Xianglin Yu. Preparation and Application of Biodegradable Superabsorbent Polymer Microspheres. Progress in Chemistry, 2026, 38(8): 1481-1489 DOI:10.7536/PC20251204

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Funding

National Natural Science Foundation of China(51203127)

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